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Preparation and Characterization of Functionalized Carbon Nanotubes/Poly(phthalazinone ether sulfone ketone)s Composites
X. B. Feng; G. X. Liao; W. He; Q. M. Sun; X. G. Jian; J. H. Du
2009
发表期刊Polymer Composites
ISSN0272-8397
卷号30期号:4页码:365-373
摘要Multiwalled carbon nanotubes (MWNT) were successfully functionalized with phthalazinone-containing diamine (DHPZDA) groups by the amidation reaction. The morphologies and structures of the DHPZDA-functionalized MWNT (MWNT-DHPZDA) were characterized by scanning electron microscope, Fourier transform infrared, and Raman spectroscopy, revealing that the DHPZDA were covalently attached onto the surface of MWNT, and the weight gain due to the functionalization was determined by thermogravimetric analysis. The MWNT-DHPZDA/poly(phthalazinone ether sulfone ketone)s (PPESK) composites with different filler content were prepared by the solution-mixing method. MWNT-DHPZDA can be uniformly dispersed in the matrix and the strong interfacial adhesion between two constituents was found, which resulted in obvious enhancements of the mechanical properties. For the composite with 1 wt% MWNT-DHPZDA, the tensile strength and the Young's modulus are 102.1 and 1,974 MPa, about 1.65 and 1.72 times of the pure PPESK, respectively. Conductivity measurements indicate that a typical percolation transition behavior takes place for MWNT-DHPZDA content in the range from 0.5 to 2 wt%. Additionally, introducing MWNT-DHPZDA into PPESK is favorable to improvement of the thermal stability. POLYM. COMPOS., 30:365-373, 2009. (C) 2008 Society of Plastics Engineers
部门归属[feng, xuebin; liao, gongxiong; he, wei; sun, qingmin; jian, xigao] dalian univ technol, dept polymer sci & mat, dalian 116012, peoples r china. [du, jinhong] chinese acad sci, shenyang natl lab mat sci, inst met res, shenyang 110016, peoples r china.;jian, xg (reprint author), dalian univ technol, dept polymer sci & mat, dalian 116012, peoples r china;jian4616@dl.cn
关键词Carbon-nanotube/siloxane/poly(Urea Urethane) Nanocomposites Nanotube-epoxy Composites Mechanical-properties Electrical-conductivity Polymer Composites Polyimide Morphology Networks Films Acid
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WOS记录号WOS:000264557400001
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被引频次:16[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/31904
专题中国科学院金属研究所
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X. B. Feng,G. X. Liao,W. He,et al. Preparation and Characterization of Functionalized Carbon Nanotubes/Poly(phthalazinone ether sulfone ketone)s Composites[J]. Polymer Composites,2009,30(4):365-373.
APA X. B. Feng,G. X. Liao,W. He,Q. M. Sun,X. G. Jian,&J. H. Du.(2009).Preparation and Characterization of Functionalized Carbon Nanotubes/Poly(phthalazinone ether sulfone ketone)s Composites.Polymer Composites,30(4),365-373.
MLA X. B. Feng,et al."Preparation and Characterization of Functionalized Carbon Nanotubes/Poly(phthalazinone ether sulfone ketone)s Composites".Polymer Composites 30.4(2009):365-373.
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