Effects of Concentration, Temperature and Hydrostatic Pressure on the Local Lattice Structure of Ni(2+) Doped Zn(BF(4))(2) center dot 6H(2)O Crystal

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	Effects of Concentration, Temperature and Hydrostatic Pressure on the Local Lattice Structure of Ni(2+) Doped Zn(BF(4))(2) center dot 6H(2)O Crystal
	M. L. Gao; X. Y. Kuang; H. F. Li; H. Q. Wang
	2009
发表期刊	Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences
ISSN	0932-0784
卷号	64 期号:7-8 页码:511-517
摘要	A theoretical method for studying the inter-relationship between electronic and molecular structure is presented by means of complete energy matrices. As an application, the effects of temperature, concentration and hydrostatic pressure on the local structures of Ni(2+) doped Zn(BF(4))(2) center dot 6H(2)O crystal have been Studied. Our results show that the local lattice structures of [Ni(H(2)O)(6)](2+) coordination complex have expansion distortions as the temperature rises. Meanwhile, we find that the local structure parameter theta becomes smaller with the increasing concentration of Ni(2+) ions doped in Zn(BF(4))(2) center dot 6H(2)O crystal. Furthermore, the pressure dependence of theta and anisotropic g-factors are discussed and the relationship between zero-field splitting parameter D and Delta g is determined.
部门归属	[gao, ming-liang; kuang, xiao-yu; li, hui-fang; wang, huai-qian] sichuan univ, inst atom & mol phys, chengdu 610065, peoples r china. [kuang, xiao-yu] acad sinica, int ctr mat phys, shenyang 100016, peoples r china.;kuang, xy (reprint author), sichuan univ, inst atom & mol phys, chengdu 610065, peoples r china;scu_kuang@163.com
关键词	Local Structure Zn(Bf(4))(2) Center Dot 6h(2)o:Ni(2+) System Complete Energy Matrices Optical-absorption Epr-spectra Mn2++ Ions Nickel Endor
URL	查看原文
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/31924
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	M. L. Gao,X. Y. Kuang,H. F. Li,et al. Effects of Concentration, Temperature and Hydrostatic Pressure on the Local Lattice Structure of Ni(2+) Doped Zn(BF(4))(2) center dot 6H(2)O Crystal[J]. Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences,2009,64(7-8):511-517.
APA	M. L. Gao,X. Y. Kuang,H. F. Li,&H. Q. Wang.(2009).Effects of Concentration, Temperature and Hydrostatic Pressure on the Local Lattice Structure of Ni(2+) Doped Zn(BF(4))(2) center dot 6H(2)O Crystal.Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences,64(7-8),511-517.
MLA	M. L. Gao,et al."Effects of Concentration, Temperature and Hydrostatic Pressure on the Local Lattice Structure of Ni(2+) Doped Zn(BF(4))(2) center dot 6H(2)O Crystal".Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences 64.7-8(2009):511-517.