Correlation between Zero-Field Splitting and Site Distortions of Cr(3+) Ions in NH(4)Cl:Cr(3+) System: a Complete Energy Matrix Study

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	Correlation between Zero-Field Splitting and Site Distortions of Cr(3+) Ions in NH(4)Cl:Cr(3+) System: a Complete Energy Matrix Study
	M. L. Gao; X. Y. Kuang; Y. R. Zhao; L. Qi; Y. F. Li
	2009
发表期刊	Chinese Physics Letters
ISSN	0256-307X
卷号	26 期号:5
摘要	A theoretical method for investigating the inter-relation between the electronic and molecular structures of 3d(3) configuration ions in a tetragonal ligand field is established on the basis of the 120 x 120 complete energy matrices. Using this method, the local structure parameters of two tetragonal Cr(3+) centers in the NH(4)Cl:Cr(3+) system are determined. Furthermore, the relations between the molecular symmetry and the ligand field symmetry are discussed.
部门归属	[gao ming-liang; kuang xiao-yu; zhao ya-ru; qi lin; li yan-fang] sichuan univ, inst atom & mol phys, chengdu 610065, peoples r china. [kuang xiao-yu] chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china.;gao, ml (reprint author), sichuan univ, inst atom & mol phys, chengdu 610065, peoples r china;scu_kuang@163.com
关键词	Electron-paramagnetic-res Single-crystals Spin Resonance Spectrum Fe-3++ Ferromagnetism Nanocrystals Centers Esr Epr
URL	查看原文
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/31925
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	M. L. Gao,X. Y. Kuang,Y. R. Zhao,et al. Correlation between Zero-Field Splitting and Site Distortions of Cr(3+) Ions in NH(4)Cl:Cr(3+) System: a Complete Energy Matrix Study[J]. Chinese Physics Letters,2009,26(5).
APA	M. L. Gao,X. Y. Kuang,Y. R. Zhao,L. Qi,&Y. F. Li.(2009).Correlation between Zero-Field Splitting and Site Distortions of Cr(3+) Ions in NH(4)Cl:Cr(3+) System: a Complete Energy Matrix Study.Chinese Physics Letters,26(5).
MLA	M. L. Gao,et al."Correlation between Zero-Field Splitting and Site Distortions of Cr(3+) Ions in NH(4)Cl:Cr(3+) System: a Complete Energy Matrix Study".Chinese Physics Letters 26.5(2009).