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Comparative Study of the Superhydrophobic-Modification of Silicone Rubber Surfaces by CF(4) ICP and CCP
S. H. Gao; K. S. Zhou; M. K. Lei; L. S. Wen
2009
发表期刊Plasma Processes and Polymers
ISSN1612-8850
卷号6期号:8页码:530-536
摘要Super-hydrophobic surface-modification of silicone rubber (SIR) as an outdoor insulator by CF(4) radio frequency (RF) inductively coupled plasma (ICP) and capacitively coupled plasma (CCP) has been studied. X-Ray photoelectron spectroscopy, atomic force microscopy, and static contact angle measurements were employed to characterize the changes of the surface chemical composition, topography, and hydrophobicity. The results show that etching or ablation and fluorination are parallel and competitive during both treatments. The improvement of hydrophobicity is ascribed to the coaction of the increase of surface roughness and the introduction of fluoric groups (C-CF(n)) or structures (Si-F and Si-F(2)). It is also found that the ratio of [Si-F]/[C-F] and the increase of surface roughness of the SIR treated by CCP are higher than that by ICP, which leads to a greater hydrophobic modification effect by the CCP process.
部门归属[gao, song-hua] sanming univ, dept phys mech & elect engn, sanming 365004, peoples r china. [gao, song-hua; zhou, ke-sheng; wen, li-shi] cent s univ, sch phys sci & technol, changsha 410083, peoples r china. [lei, ming-kai; wen, li-shi] dalian univ technol, sch mat sci & engn, dalian 116024, peoples r china. [wen, li-shi] chinese acad sci, inst met res, shenyang 110016, peoples r china.;gao, sh (reprint author), sanming univ, dept phys mech & elect engn, sanming 365004, peoples r china;gaosonghua2005@126.com
关键词Afm Cf(4) Icp And Ccp Silicon Rubber Superhydrophobic Modification Surface Modification Xps Plasma Treatment Outdoor Insulators Gas Plasma Polymers Films Fluorination Energy
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/31927
专题中国科学院金属研究所
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S. H. Gao,K. S. Zhou,M. K. Lei,et al. Comparative Study of the Superhydrophobic-Modification of Silicone Rubber Surfaces by CF(4) ICP and CCP[J]. Plasma Processes and Polymers,2009,6(8):530-536.
APA S. H. Gao,K. S. Zhou,M. K. Lei,&L. S. Wen.(2009).Comparative Study of the Superhydrophobic-Modification of Silicone Rubber Surfaces by CF(4) ICP and CCP.Plasma Processes and Polymers,6(8),530-536.
MLA S. H. Gao,et al."Comparative Study of the Superhydrophobic-Modification of Silicone Rubber Surfaces by CF(4) ICP and CCP".Plasma Processes and Polymers 6.8(2009):530-536.
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