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Lithium zincopyrophosphate, Li(2)Zn(3)(P(2)O(7))(2)
L. N. Ji; H. W. Ma; J. K. Liang
2009
发表期刊Acta Crystallographica Section C-Crystal Structure Communications
ISSN0108-2701
卷号65页码:I30-I32
摘要The title compound, dilithium(I) trizinc(II) bis[diphosphate(4-)], is the first quaternary lithium zincopyrophosphate in the Li-Zn-P-O system. It features zigzag chains running along c, which are built up from edge-sharing [ZnO(5)] trigonal bipyramids. One of the two independent Zn sites is fully occupied, whereas the other is statistically disordered by Zn(2+) and Li(+) cations, although the two Zn sites have similar coordination environments. Li(+) cations occupy a four-coordinated independent site with an occupancy factor of 0.5, as well as being disordered on the partially occupied five-coordinated Zn site with a Zn(2+)/Li(+) ratio of 1:1.
部门归属[ma, hongwei] indiana univ, dept geol sci, bloomington, in 47405 usa. [ji, lina; liang, jingkui] chinese acad sci, inst phys, beijing 100080, peoples r china. [liang, jingkui] acad sinica, int ctr mat phys, shenyang 110016, peoples r china.;ma, hw (reprint author), indiana univ, dept geol sci, 1001 e 10th st, bloomington, in 47405 usa;hongma@indiana.edu
关键词Zinc Phosphate Polymorph Zno
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/31991
专题中国科学院金属研究所
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L. N. Ji,H. W. Ma,J. K. Liang. Lithium zincopyrophosphate, Li(2)Zn(3)(P(2)O(7))(2)[J]. Acta Crystallographica Section C-Crystal Structure Communications,2009,65:I30-I32.
APA L. N. Ji,H. W. Ma,&J. K. Liang.(2009).Lithium zincopyrophosphate, Li(2)Zn(3)(P(2)O(7))(2).Acta Crystallographica Section C-Crystal Structure Communications,65,I30-I32.
MLA L. N. Ji,et al."Lithium zincopyrophosphate, Li(2)Zn(3)(P(2)O(7))(2)".Acta Crystallographica Section C-Crystal Structure Communications 65(2009):I30-I32.
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