Modeling influence of gas/liquid/solid three-phase boundary zone on cathodic process of soil corrosion | |
J. Jiang; J. Wang; W. W. Wang; W. Zhang | |
2009 | |
发表期刊 | Electrochimica Acta
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ISSN | 0013-4686 |
卷号 | 54期号:13页码:3623-3629 |
摘要 | Geometric properties of gas/liquid/solid three-phase boundary (TPB) zones of dispersive liquid on a metal surface in soils, play an important role in the cathodic and corrosion behavior of metals. The correlation between the TPB geometric parameters (e.g. its length and width) and the soil water content is established, and on this basis, the influence of TPB parameters on the cathodic oxygen reduction process of soil corrosion is simulated. The simulation result shows an initial increase and a subsequent decrease in cathodic limiting current with increasing soil water content, and a maximum is present at about 60% water content of their water holding capacity (WHC), in good agreement with the experimental results. In addition, a parameter b is proposed to evaluate the liquid dispersion in soils, and a linear dependence of cathodic limiting current on parameter b is calculated from the model, confirming the important role of liquid dispersion in soil corrosion systems. (C) 2009 Elsevier Ltd. All rights reserved. |
部门归属 | [jiang, jing; wang, jia; wang, weiwei; zhang, wei] ocean univ qingdao, qingdao 266100, peoples r china. [wang, jia] state key lab corros & protect met, shenyang 110016, peoples r china. [wang, weiwei] qblsmri, state key lab marine corros & protect, qingdao 266071, peoples r china.;wang, j (reprint author), ocean univ qingdao, qingdao 266100, peoples r china;jwang@mail.ouc.edu.cn |
关键词 | Three-phase Boundary Zone Tpb Parameters Soil Water Content Cathodic Limiting Current Modeling Moisture-content Steel |
URL | 查看原文 |
WOS记录号 | WOS:000265701100020 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/31998 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | J. Jiang,J. Wang,W. W. Wang,et al. Modeling influence of gas/liquid/solid three-phase boundary zone on cathodic process of soil corrosion[J]. Electrochimica Acta,2009,54(13):3623-3629. |
APA | J. Jiang,J. Wang,W. W. Wang,&W. Zhang.(2009).Modeling influence of gas/liquid/solid three-phase boundary zone on cathodic process of soil corrosion.Electrochimica Acta,54(13),3623-3629. |
MLA | J. Jiang,et al."Modeling influence of gas/liquid/solid three-phase boundary zone on cathodic process of soil corrosion".Electrochimica Acta 54.13(2009):3623-3629. |
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