A study on the hydrogen-storage properties of La(2-x)Ti(x)MgNi(9) (x=0.1, 0.2, 0.3, 0.4) alloys | |
W. Q. Jiang; Z. Q. Lan; L. Q. Xu; G. X. Lia; J. Guo | |
2009 | |
发表期刊 | International Journal of Hydrogen Energy
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ISSN | 0360-3199 |
卷号 | 34期号:11页码:4827-4832 |
摘要 | The La(2-x)Ti(x)MgNi(9) (x = 0.1, 0.2, 0.3, 0.4) alloys were prepared by magnetic levitation melting under Ar atmosphere. The effects of partial substitution Ti for La on the phase structures, hydrogen-storage proper-ties and electrochemical characteristics of the alloys were investigated systematically. For La(2-x)Ti(x)MgNi(9) (x = 0.1, 0.2, 0.3, 0.4) alloys, LaNi(5), LaNi(3) and LaMg(2)Ni(9) are the main phases, the maximum hydrogen-storage capacity is 1.51, 1.36, 1.35 and 1.22 wt%, respectively. The absorption-desorption plateau pressure of the alloys first decreases and then increases with increase of Ti content, and the La(1.8)MgTi(0.2)Ni(9) alloy has the lowest absorption-desorption plateau pressure. The discharge voltage of the alloy electrodes rises with increasing the amount of Ti content. The La(1.8)Ti(0.2)MgNi(9) alloy electrode presents good electrochemical performance. (C) 2009 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved. |
部门归属 | [jiang, weiqing; lan, zhiqiang; xu, liqin; lia, guangxu; guo, jin] guangxi univ, coll phys sci & technol, nanning 530004, peoples r china. [guo, jin] chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china.;guo, j (reprint author), guangxi univ, coll phys sci & technol, nanning 530004, peoples r china;guojin@gxu.edu.cn |
关键词 | Hydrogen-storage Alloy Hydrogen-storage Property Electrochemical Characteristic Electrochemical Properties Electrode Alloys Substitution Mn La Ni Co Zr Al Microstructures |
URL | 查看原文 |
WOS记录号 | WOS:000267562100015 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/32001 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | W. Q. Jiang,Z. Q. Lan,L. Q. Xu,et al. A study on the hydrogen-storage properties of La(2-x)Ti(x)MgNi(9) (x=0.1, 0.2, 0.3, 0.4) alloys[J]. International Journal of Hydrogen Energy,2009,34(11):4827-4832. |
APA | W. Q. Jiang,Z. Q. Lan,L. Q. Xu,G. X. Lia,&J. Guo.(2009).A study on the hydrogen-storage properties of La(2-x)Ti(x)MgNi(9) (x=0.1, 0.2, 0.3, 0.4) alloys.International Journal of Hydrogen Energy,34(11),4827-4832. |
MLA | W. Q. Jiang,et al."A study on the hydrogen-storage properties of La(2-x)Ti(x)MgNi(9) (x=0.1, 0.2, 0.3, 0.4) alloys".International Journal of Hydrogen Energy 34.11(2009):4827-4832. |
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