Hydrogen Generation from Catalytic Hydrolysis of Sodium Borohydride Solution

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	Hydrogen Generation from Catalytic Hydrolysis of Sodium Borohydride Solution
	Y. Liang; P. Wang; H. B. Dai
	2009
发表期刊	Progress in Chemistry
ISSN	1005-281X
卷号	21 期号:10 页码:2219-2228
摘要	Hydrogen generation (HG) from catalytic hydrolysis of sodium borohydride (NaBH(4)) solution is a promising integrated technology for on-board hydrogen storage/generation. In this paper, we present the principle of HG from NaBH(4) solution, and review the current progresses in catalysts, reaction kinetics, reaction mechanism, design of reaction generator and recycle of hydrolysis production, and then discuss some remaining problems in the development of NaBH(4)-based HG system. Supported catalyst with high-activity and durability is desirable in developing the HG system for practical application. The design of hydrogen generator focuses on the utilization of reaction heat to preheat fuel, the recycle of water from the fuel cells and the technology of separation by the membrane. The highly efficient regeneration of NaBH(4) can reduce its cost, thus promoting the commercial applications of the NaBH(4)-based HG system.
部门归属	[liang yan; wang ping; dai hongbin] chinese acad sci, shenyang natl lab mat sci, inst met res, shenyang 110016, peoples r china.;dai, hb (reprint author), chinese acad sci, shenyang natl lab mat sci, inst met res, shenyang 110016, peoples r china;hbdai@imr.ac.cn
关键词	Sodium Borohydride Hydrogen Storage/generation Catalysts Reaction Kinetics Hydrogen Generator Pulsed-laser Deposition Alkaline Nabh4 Solution Supported Cobalt Catalyst B-11 Nmr Measurements Fuel-cell Generators Co-b Catalyst Thin-films Ruthenium(0) Nanoclusters Electroless Deposition Dimethylamine Borane
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WOS记录号	WOS:000270877800026
引用统计	被引频次：8[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/32053
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	Y. Liang,P. Wang,H. B. Dai. Hydrogen Generation from Catalytic Hydrolysis of Sodium Borohydride Solution[J]. Progress in Chemistry,2009,21(10):2219-2228.
APA	Y. Liang,P. Wang,&H. B. Dai.(2009).Hydrogen Generation from Catalytic Hydrolysis of Sodium Borohydride Solution.Progress in Chemistry,21(10),2219-2228.
MLA	Y. Liang,et al."Hydrogen Generation from Catalytic Hydrolysis of Sodium Borohydride Solution".Progress in Chemistry 21.10(2009):2219-2228.