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Corrosion protection of AZ91D magnesium alloy with sol-gel coating containing 2-methyl piperidine; Corrosion protection of AZ91D magnesium alloy with sol-gel coating containing 2-methyl piperidine
H. W. Shi; F. C. Liu; E. H. Han
2009 ; 2009
Source PublicationProgress in Organic Coatings ; Progress in Organic Coatings
ISSN0300-9440 ; 0300-9440
Volume66Issue:3Pages:183-191
AbstractSol-gel coatings were prepared using 3-glycidoxypropyltrimethoxysilane (GPTMS) and tetraethoxysilane (TMOS) as precursors, diethylentriamine as curing agent. Inhibition effect of 2-methyl piperidine on AZ91D in 0.005%, 0.05% and 0.5% (wt.%) NaCl solution is investigated. Potentiodynamic polarization tests revealed that 2-methyl piperidine significantly decreased the anodic activity of AZ91D especially at high concentration. Corrosion behaviors of sol-gel coatings incorporated with 2-methyl piperidine on AZ91D in the Harrison's solution were analyzed using electrochemical impedance spectroscopy (EIS). EIS results showed the corrosion resistance of sol-gel coatings and sol-gel sealed phosphate conversion coating on AZ91D were significantly improved through addition of 2-methyl piperidine. Fourier transform infrared spectra (FT-IR) confirmed that the 2-methyl piperidine was compatible with sol-gel matrix. (C) 2009 Elsevier B.V. All rights reserved.; Sol-gel coatings were prepared using 3-glycidoxypropyltrimethoxysilane (GPTMS) and tetraethoxysilane (TMOS) as precursors, diethylentriamine as curing agent. Inhibition effect of 2-methyl piperidine on AZ91D in 0.005%, 0.05% and 0.5% (wt.%) NaCl solution is investigated. Potentiodynamic polarization tests revealed that 2-methyl piperidine significantly decreased the anodic activity of AZ91D especially at high concentration. Corrosion behaviors of sol-gel coatings incorporated with 2-methyl piperidine on AZ91D in the Harrison's solution were analyzed using electrochemical impedance spectroscopy (EIS). EIS results showed the corrosion resistance of sol-gel coatings and sol-gel sealed phosphate conversion coating on AZ91D were significantly improved through addition of 2-methyl piperidine. Fourier transform infrared spectra (FT-IR) confirmed that the 2-methyl piperidine was compatible with sol-gel matrix. (C) 2009 Elsevier B.V. All rights reserved.
description.department[shi, hongwei; liu, fuchun; han, en-hou] chinese acad sci, state key lab corros & protect, inst metal res, shenyang 110016, peoples r china.;liu, fc (reprint author), chinese acad sci, state key lab corros & protect, inst metal res, shenyang 110016, peoples r china;fcliu@imr.ac.cn ; [shi, hongwei; liu, fuchun; han, en-hou] chinese acad sci, state key lab corros & protect, inst metal res, shenyang 110016, peoples r china.;liu, fc (reprint author), chinese acad sci, state key lab corros & protect, inst metal res, shenyang 110016, peoples r china;fcliu@imr.ac.cn
KeywordSol-gel Coatings Sol-gel Coatings Magnesium Alloy Magnesium Alloy Inhibitor Inhibitor Corrosion Corrosion Parameters Parameters Resistance Resistance Inhibitors Inhibitors Aa2024-t3 Aa2024-t3 Films Films
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WOS IDWOS:000271366200002 ; WOS:000271366200002
Citation statistics
Cited Times:47[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/32279
Collection中国科学院金属研究所
Recommended Citation
GB/T 7714
H. W. Shi,F. C. Liu,E. H. Han. Corrosion protection of AZ91D magnesium alloy with sol-gel coating containing 2-methyl piperidine, Corrosion protection of AZ91D magnesium alloy with sol-gel coating containing 2-methyl piperidine[J]. Progress in Organic Coatings, Progress in Organic Coatings,2009, 2009,66, 66(3):183-191, 183-191.
APA H. W. Shi,F. C. Liu,&E. H. Han.(2009).Corrosion protection of AZ91D magnesium alloy with sol-gel coating containing 2-methyl piperidine.Progress in Organic Coatings,66(3),183-191.
MLA H. W. Shi,et al."Corrosion protection of AZ91D magnesium alloy with sol-gel coating containing 2-methyl piperidine".Progress in Organic Coatings 66.3(2009):183-191.
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