Effects of temperature on the oxide film properties of 304 stainless steel in high temperature lithium borate buffer solution

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	Effects of temperature on the oxide film properties of 304 stainless steel in high temperature lithium borate buffer solution; Effects of temperature on the oxide film properties of 304 stainless steel in high temperature lithium borate buffer solution
	H. Sun; X. Q. Wu; E. H. Han
	2009 ; 2009
发表期刊	Corrosion Science ; Corrosion Science
ISSN	0010-938X ; 0010-938X
卷号	51 期号:12 页码:2840-2847
摘要	The paper mainly investigated the effects of temperature on the oxide film properties of 304SS in lithium borate buffer solution by electrochemical measurements and XPS analysis. As temperature increased, the protective property of the film degraded and structure varied from a single layer to a double-layer. Whatever the temperature, the oxide film exhibited an n-type and p-type semiconductor in the potential range above and below the flat band potential, respectively. The electronic properties were assigned to a Fe-Cr spinel inner layer and a defective Fe-Cr oxide outer layer. The related growth mechanisms of the oxide film were also discussed. (C) 2009 Elsevier Ltd. All rights reserved.; The paper mainly investigated the effects of temperature on the oxide film properties of 304SS in lithium borate buffer solution by electrochemical measurements and XPS analysis. As temperature increased, the protective property of the film degraded and structure varied from a single layer to a double-layer. Whatever the temperature, the oxide film exhibited an n-type and p-type semiconductor in the potential range above and below the flat band potential, respectively. The electronic properties were assigned to a Fe-Cr spinel inner layer and a defective Fe-Cr oxide outer layer. The related growth mechanisms of the oxide film were also discussed. (C) 2009 Elsevier Ltd. All rights reserved.
部门归属	[sun, hua; wu, xinqiang; han, en-hou] chinese acad sci, inst met res, state key lab corros & protect, shenyang 110016, peoples r china.;wu, xq (reprint author), chinese acad sci, inst met res, state key lab corros & protect, south campus,62 wencui rd, shenyang 110016, peoples r china;xqwu@imr.ac.cn ; [sun, hua; wu, xinqiang; han, en-hou] chinese acad sci, inst met res, state key lab corros & protect, shenyang 110016, peoples r china.;wu, xq (reprint author), chinese acad sci, inst met res, state key lab corros & protect, south campus,62 wencui rd, shenyang 110016, peoples r china;xqwu@imr.ac.cn
关键词	Stainless Steel Stainless Steel Polarization Polarization Eis Eis Xps Xps Anodic Films Anodic Films 316l Stainless-steel 316l Stainless-steel Passive Films Passive Films Chemical-composition Chemical-composition Supercritical Supercritical Water Water Semiconducting Properties Semiconducting Properties Aisi 304-stainless-steel Aisi 304-stainless-steel Elevated-temperatures Elevated-temperatures Electronic-structure Electronic-structure Aqueous-solutions Aqueous-solutions Corrosion Corrosion
URL	查看原文 ; 查看原文
WOS记录号	WOS:000272742600007 ; WOS:000272742600007
引用统计	被引频次：146[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/32302
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	H. Sun,X. Q. Wu,E. H. Han. Effects of temperature on the oxide film properties of 304 stainless steel in high temperature lithium borate buffer solution, Effects of temperature on the oxide film properties of 304 stainless steel in high temperature lithium borate buffer solution[J]. Corrosion Science, Corrosion Science,2009, 2009,51, 51(12):2840-2847, 2840-2847.
APA	H. Sun,X. Q. Wu,&E. H. Han.(2009).Effects of temperature on the oxide film properties of 304 stainless steel in high temperature lithium borate buffer solution.Corrosion Science,51(12),2840-2847.
MLA	H. Sun,et al."Effects of temperature on the oxide film properties of 304 stainless steel in high temperature lithium borate buffer solution".Corrosion Science 51.12(2009):2840-2847.