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Synthesis of Graphene Sheets with High Electrical Conductivity and Good Thermal Stability by Hydrogen Arc Discharge Exfoliation
Z. S. Wu; W. C. Ren; L. B. Gao; J. P. Zhao; Z. P. Chen; B. L. Liu; D. M. Tang; B. Yu; C. B. Jiang; H. M. Cheng
2009
发表期刊Acs Nano
ISSN1936-0851
卷号3期号:2页码:411-417
摘要We developed a hydrogen arc discharge exfoliation method for the synthesis of graphene sheets (GSs) with excellent electrical conductivity and good thermal stability from graphite oxide (GO), in combination with solution-phase dispersion and centrifugation techniques. It was found that efficient exfoliation and considerable deoxygenation of GO, and defect elimination and healing of exfoliated graphite can be simultaneously achieved during the hydrogen arc discharge exfoliation process. The GSs obtained by hydrogen arc discharge exfoliation exhibit a high electrical conductivity of similar to 2 x 10(3) S/cm and high thermal stability with oxidization resistance temperature of 601 degrees C, which are much better than those prepared by argon arc discharge exfoliation (similar to 2 x 10(2) S/cm, 525 degrees C) and by conventional thermal exfoliation (similar to 80 S/cm, 507 degrees C) with the same starting GO. These results demonstrate that this hydrogen arc discharge exfoliation method is a good approach for the preparation of GSs with a good quality.
部门归属[wu, zhong-shuai; ren, wencai; gao, libo; zhao, jinping; chen, zongping; liu, bilu; tang, daiming; yu, bing; jiang, chuanbin; cheng, hui-ming] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china.;ren, wc (reprint author), chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china;wcren@imr.ac.cn cheng@imr.ac.cn
关键词Graphene Synthesis Arc Discharge Exfoliation Electrical Conductivity Thermal Stability Walled Carbon Nanotubes Functionalized Graphene Graphite Oxide Epitaxial Graphene Raman-spectroscopy Solar-cells Films Transparent Nanocomposites Electrodes
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WOS记录号WOS:000263696100024
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被引频次:790[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/32440
专题中国科学院金属研究所
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GB/T 7714
Z. S. Wu,W. C. Ren,L. B. Gao,et al. Synthesis of Graphene Sheets with High Electrical Conductivity and Good Thermal Stability by Hydrogen Arc Discharge Exfoliation[J]. Acs Nano,2009,3(2):411-417.
APA Z. S. Wu.,W. C. Ren.,L. B. Gao.,J. P. Zhao.,Z. P. Chen.,...&H. M. Cheng.(2009).Synthesis of Graphene Sheets with High Electrical Conductivity and Good Thermal Stability by Hydrogen Arc Discharge Exfoliation.Acs Nano,3(2),411-417.
MLA Z. S. Wu,et al."Synthesis of Graphene Sheets with High Electrical Conductivity and Good Thermal Stability by Hydrogen Arc Discharge Exfoliation".Acs Nano 3.2(2009):411-417.
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