Magnetic properties and quantum phase transitions of purely organic molecule-based ferrimagnets based on Green's function theory

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	Magnetic properties and quantum phase transitions of purely organic molecule-based ferrimagnets based on Green's function theory
	H. H. Fu; K. L. Yao; Z. L. Liu
	2008
发表期刊	Journal of Chemical Physics
ISSN	0021-9606
卷号	128 期号:11
摘要	Magnetic properties of a Heisenberg diamondlike spin chain model for purely organic molecule-based ferrimagnets are investigated by means of the many-body Green's function method within random phase approximation. The molecule-based ferrimagnet is composed of S=1 biradical and S=1/2 monoradical molecules alternating with intermolecular antiferromagnetic (AF) interactions, and the S=1 site is composed of two S=1/2 spins by a finite intramolecular ferromagnetic (F) interaction. The numerical results reveal that occurrence of ferrimagnetic spin alignments along the chain is determined by the intermolecular AF interactions. Owing to the very small intermolecular AF interactions, the curves of the product of magnetic susceptibility and temperature (chi T) against temperature display as a round peak at low temperatures, and the ferrimagnetic phase transition could only be detected at ultralow temperatures in practical organic compounds. Temperature- and magnetic-field-induced magnetic phase transitions are discussed, which are consistent with the experimental findings. The lower spatial symmetry of intermolecular interactions makes it easy to form spin pairs with a singlet (S=0) ground state along the chain and to reduce Curie temperature. The formations of molecular dimers and trimers along the chain have contributions to bring about F alignments with effective S=1/2 magnetic supramolecules and to enhance Curie temperature. In addition, the experimental data of the magnetic susceptibility measurements for a molecule-based ferrimagnet are also fairly compared with our theoretical results.
部门归属	[fu, hua-hua; yao, kai-lun; liu, zu-li] huazhong univ sci & technol, dept phys, wuhan 430074, peoples r china. [yao, kai-lun] chinese acad sci, int ctr mat phys, shenyang 110015, peoples r china. [liu, zu-li] nanjing univ, state key lab coordinat chem, nanjing 210093, peoples r china.;fu, hh (reprint author), huazhong univ sci & technol, dept phys, wuhan 430074, peoples r china, peoples r china;fuhust@yahoo.com.cn klyao@mail.hust.edu.cn
关键词	State Singlet Biradicals Ground-state Numerical-calculations Nitronyl Nitroxide Ferromagnetism Chains Heat
URL	查看原文
WOS记录号	WOS:000254292500055
引用统计	被引频次：18[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/32760
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	H. H. Fu,K. L. Yao,Z. L. Liu. Magnetic properties and quantum phase transitions of purely organic molecule-based ferrimagnets based on Green's function theory[J]. Journal of Chemical Physics,2008,128(11).
APA	H. H. Fu,K. L. Yao,&Z. L. Liu.(2008).Magnetic properties and quantum phase transitions of purely organic molecule-based ferrimagnets based on Green's function theory.Journal of Chemical Physics,128(11).
MLA	H. H. Fu,et al."Magnetic properties and quantum phase transitions of purely organic molecule-based ferrimagnets based on Green's function theory".Journal of Chemical Physics 128.11(2008).