Influence of calcining temperature on photoresponse of TiO2 film under nitrogen and oxygen in room temperature

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	Influence of calcining temperature on photoresponse of TiO2 film under nitrogen and oxygen in room temperature
	S. A. Gao; A. P. Man; L. H. Cao; R. C. Xie; J. K. Shang
	2008
发表期刊	Sensors and Actuators B-Chemical
ISSN	0925-4005
卷号	134 期号:2 页码:718-726
摘要	The photoresponse of TiO2 in nitrogen and oxygen under visible light was studied. The TiO2 Was synthesized by a new sol-gel process using Ti(OBu)(4) and ethanolamine, while the research was focused on the effect of calcining temperature on the photoresponse of the TiO2 film. It was observed a strong photoresponse of the TiO2 at a light wavelength of approximately 480 nm in room temperature when calcined at temperature from 450 to 500,C. On the contrary, the photoreponse was very weak for TiO2 calcined at temperature less than 400 degrees C or more than 550 degrees C. Thermal gravimetry-differential scanning calorimeter-mass spectrometer (TG-DSC-MS) measurement showed that there was a significant weight loss (about 18 wt.%) of the TiO2 precursor calcined in the temperature range from 400 to 470 degrees C, which was due to the oxidation of the residual impurities in the TiO2. The evolved gases were primarily composed of H2O and CO2. In conclusion, it is suggested that the strong photoresponse of the TiO2 under visible light is due to the impurities, such as carbon or hydrocarbon compound which mixed with or adhered on the TiO2, as well as the microporous structure in the TiO2 film (C) 2008 Elsevier BY. All rights reserved.
部门归属	[gao, shi-an; man, ai-ping; cao, li-hua; xie, rong-cai; shang, jian-ku] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china.;man, ap (reprint author), chinese acad sci, inst met res, shenyang natl lab mat sci, 72 wenhua rd, shenyang 110016, peoples r china, peoples r china;ap.xian@imr.ac.cn
关键词	Tio2 Sol-gel Photoresponse Sensor Processing Titanium-dioxide Photocatalytic Activity Mesoporous Tio2 Band-gap Sensor Oxide
URL	查看原文
WOS记录号	WOS:000260147100059
引用统计	被引频次：16[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/32773
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	S. A. Gao,A. P. Man,L. H. Cao,et al. Influence of calcining temperature on photoresponse of TiO2 film under nitrogen and oxygen in room temperature[J]. Sensors and Actuators B-Chemical,2008,134(2):718-726.
APA	S. A. Gao,A. P. Man,L. H. Cao,R. C. Xie,&J. K. Shang.(2008).Influence of calcining temperature on photoresponse of TiO2 film under nitrogen and oxygen in room temperature.Sensors and Actuators B-Chemical,134(2),718-726.
MLA	S. A. Gao,et al."Influence of calcining temperature on photoresponse of TiO2 film under nitrogen and oxygen in room temperature".Sensors and Actuators B-Chemical 134.2(2008):718-726.