Investigation of the Local Lattice Structure and the Effects of the Orbital Reduction Factor on the g Factors of a Trigonal Ni(H2O)(6) (2)+ Cluster in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O Crystals at Different Temperatures

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	Investigation of the Local Lattice Structure and the Effects of the Orbital Reduction Factor on the g Factors of a Trigonal Ni(H2O)(6) (2)+ Cluster in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O Crystals at Different Temperatures
	H. F. Li; X. Y. Kuang; H. Q. Wang; A. J. Mao
	2008
Source Publication	Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences
ISSN	0932-0784
Volume	63 Issue:9 Pages:609-615
Abstract	The local octahedral environment of Ni2+ in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O crystals with a trigonal distortion has been studied at different temperatures, based on the complete energy matrices. The calculated results showed that the local lattice structure around an octahedral Ni2+ centre in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O exhibits at compression distortion. Simultaneously, the orbital reduction effect on the g factors has been studied. The relationship between Ag =g(parallel to) -g(perpendicular to) and orbital reduction fractor k at 4.2.77 and 298 (302) K has been discussed. suggesting, that there is an almost linear relation between k and Delta g in Ni2+ ion in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O at each temperature.
description.department	[li, hu-fang; kuang, xiao-yu; wang, huai-qian; mao, ai-jie] sichuan univ, inst atom & mol phys, chengdu 610065, peoples r china. [kuang, xiao-yu] acad sinica, int ctr mat phys, shenyang 110016, peoples r china.;li, hf (reprint author), sichuan univ, inst atom & mol phys, chengdu 610065, peoples r china;seu_kxy@163.com
Keyword	Local Structure Orbital Reduction Effect Epr Spectrum Complete Energy Matrices Electron-paramagnetic-resonance Nickel Fluosilicate Spectra Zinc
URL	查看原文
Document Type	期刊论文
Identifier	http://ir.imr.ac.cn/handle/321006/32865
Collection	中国科学院金属研究所
Recommended Citation GB/T 7714	H. F. Li,X. Y. Kuang,H. Q. Wang,et al. Investigation of the Local Lattice Structure and the Effects of the Orbital Reduction Factor on the g Factors of a Trigonal Ni(H2O)(6) (2)+ Cluster in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O Crystals at Different Temperatures[J]. Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences,2008,63(9):609-615.
APA	H. F. Li,X. Y. Kuang,H. Q. Wang,&A. J. Mao.(2008).Investigation of the Local Lattice Structure and the Effects of the Orbital Reduction Factor on the g Factors of a Trigonal Ni(H2O)(6) (2)+ Cluster in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O Crystals at Different Temperatures.Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences,63(9),609-615.
MLA	H. F. Li,et al."Investigation of the Local Lattice Structure and the Effects of the Orbital Reduction Factor on the g Factors of a Trigonal Ni(H2O)(6) (2)+ Cluster in NiTiF6 center dot 6H(2)O and ZnSiF6 center dot 6H(2)O Crystals at Different Temperatures".Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences 63.9(2008):609-615.

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