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The effect of beta-FeOOH on the corrosion behavior of low carbon steel exposed in tropic marine environment
Y. T. Ma; Y. Li; F. H. Wang
2008
发表期刊Materials Chemistry and Physics
ISSN0254-0584
卷号112期号:3页码:844-852
摘要The atmospheric corrosion performance of carbon steel exposed in Warming area, which located in the south part of China with tropic marine environment characters, was studied at different exposure periods (up to 2 years). To investigate the effect of beta-FeOOH on the corrosion behavior of carbon steel in high chloride ion environment, rust layer was analyzed by using infrared spectroscopy, scanning electron microscope, X-ray diffraction, and the rusted steel was measured by electrochemical impedance spectroscopy method. The weight loss test indicated that the corrosion rate of carbon steel sharply increased during 6 months' exposure and gradually reduced after longer exposure. The results of rust analysis revealed that the underlying corrosion performance of the carbon steel was dependent on the inherent properties of the rust layers formed under different conditions such as composition and structure. Among all the iron oxide, beta-FeOOH exerted significant influence. The presence of a monolayer of the rust as well as beta-FeOOH accelerated the corrosion process during the initial exposure stage. EIS data implied that beta-FeOOH in the inner layer was gradually consumed and transformed to gamma-Fe(2)O(3) in the wet-dry cycle, which was beneficial to protect the substrate and reduced the corrosion rate. (C) 2008 Elsevier B.V. All rights reserved.
部门归属[ma, yuantai; li, ying; wang, fuhui] chinese acad sci, inst met res, state key lab corros & protect, shenyang 110016, peoples r china.;li, y (reprint author), chinese acad sci, inst met res, state key lab corros & protect, wencui rd 62, shenyang 110016, peoples r china;liying@imr.ac.cn
关键词Corrosion Monolayer Oxide Infrared Spectroscopy Weathering Steel Rust Layer Impedance Spectroscopy Atmospheric Corrosion Synchrotron-radiation Protective Ability Interface Water Iron Temperature
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WOS记录号WOS:000262183900026
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被引频次:139[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/33024
专题中国科学院金属研究所
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Y. T. Ma,Y. Li,F. H. Wang. The effect of beta-FeOOH on the corrosion behavior of low carbon steel exposed in tropic marine environment[J]. Materials Chemistry and Physics,2008,112(3):844-852.
APA Y. T. Ma,Y. Li,&F. H. Wang.(2008).The effect of beta-FeOOH on the corrosion behavior of low carbon steel exposed in tropic marine environment.Materials Chemistry and Physics,112(3),844-852.
MLA Y. T. Ma,et al."The effect of beta-FeOOH on the corrosion behavior of low carbon steel exposed in tropic marine environment".Materials Chemistry and Physics 112.3(2008):844-852.
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