Characterization of protective performance of epoxy reinforced with nanometer-sized TiO2 and SiO2; Characterization of protective performance of epoxy reinforced with nanometer-sized TiO2 and SiO2 | |
H. W. Shi; F. C. Liu; L. H. Yang; E. H. Han | |
2008 ; 2008 | |
发表期刊 | Progress in Organic Coatings
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ISSN | 0300-9440 ; 0300-9440 |
卷号 | 62期号:4页码:359-368 |
摘要 | Nano-TiO2 particles was uniformly dispersed and prepared into concentrated nano-paste. The effects of nano-TiO2 particles on the performance of epoxy resin on 2024-T3 aluminum alloy were investigated. The effects of nano-SiO2 with gamma-glycidoxypropyltrimethoxy silane modification or without modification on the performance of epoxy resin were also studied. It was found that the hardness of epoxy resin was improved by the incorporation of 1 wt.% nano-TiO2 particles or nano-SiO2. The results of electrochemical impedance spectrum (EIS) and salt spray test indicated that the addition of nano-TiO2/SiO2 significantly improved the corrosion resistance of epoxy resin. Fourier transform infrared spectra (FT-IR) proved that the new absorptions at 1070 and 1090cm(-1) on silane-treated nano-SiO2 particles, which can evidence the ring structure of Si-O-Si. The formation of layered ring structure of nano-SiO2 can be explained for the enhancement of the corrosion resistance and hardness of nano-SiO2/epoxy composite. (C) 2007 Elsevier B.V. All rights reserved.; Nano-TiO2 particles was uniformly dispersed and prepared into concentrated nano-paste. The effects of nano-TiO2 particles on the performance of epoxy resin on 2024-T3 aluminum alloy were investigated. The effects of nano-SiO2 with gamma-glycidoxypropyltrimethoxy silane modification or without modification on the performance of epoxy resin were also studied. It was found that the hardness of epoxy resin was improved by the incorporation of 1 wt.% nano-TiO2 particles or nano-SiO2. The results of electrochemical impedance spectrum (EIS) and salt spray test indicated that the addition of nano-TiO2/SiO2 significantly improved the corrosion resistance of epoxy resin. Fourier transform infrared spectra (FT-IR) proved that the new absorptions at 1070 and 1090cm(-1) on silane-treated nano-SiO2 particles, which can evidence the ring structure of Si-O-Si. The formation of layered ring structure of nano-SiO2 can be explained for the enhancement of the corrosion resistance and hardness of nano-SiO2/epoxy composite. (C) 2007 Elsevier B.V. All rights reserved. |
部门归属 | [shi, hongwei; liu, fuchun; yang, lihong; han, enhou] chinese acad sci, inst met res, environm corros ctr, shenyang 110016, peoples r china.;han, eh (reprint author), chinese acad sci, inst met res, environm corros ctr, shenyang 110016, peoples r china;ehhan@imr.ac.cn ; [shi, hongwei; liu, fuchun; yang, lihong; han, enhou] chinese acad sci, inst met res, environm corros ctr, shenyang 110016, peoples r china.;han, eh (reprint author), chinese acad sci, inst met res, environm corros ctr, shenyang 110016, peoples r china;ehhan@imr.ac.cn |
关键词 | Electrochemical Impedance Spectrum Electrochemical Impedance Spectrum Nano-tio2 Nano-tio2 Nano-sio2 Nano-sio2 Glass Glass Transition Temperature Transition Temperature Fourier Transform Infrared Spectra Fourier Transform Infrared Spectra Curing Agents Curing Agents Resin Resin Nanocomposites Nanocomposites Particles Particles Impedance Impedance Coatings Coatings Behavior Behavior Metals Metals |
URL | 查看原文 ; 查看原文 |
WOS记录号 | WOS:000256565400001 ; WOS:000256565400001 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/33071 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | H. W. Shi,F. C. Liu,L. H. Yang,et al. Characterization of protective performance of epoxy reinforced with nanometer-sized TiO2 and SiO2, Characterization of protective performance of epoxy reinforced with nanometer-sized TiO2 and SiO2[J]. Progress in Organic Coatings, Progress in Organic Coatings,2008, 2008,62, 62(4):359-368, 359-368. |
APA | H. W. Shi,F. C. Liu,L. H. Yang,&E. H. Han.(2008).Characterization of protective performance of epoxy reinforced with nanometer-sized TiO2 and SiO2.Progress in Organic Coatings,62(4),359-368. |
MLA | H. W. Shi,et al."Characterization of protective performance of epoxy reinforced with nanometer-sized TiO2 and SiO2".Progress in Organic Coatings 62.4(2008):359-368. |
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