| Alloy compositions of metallic glasses and eutectics from an idealized structural model |
| L. L. Shi; J. Xu; E. Ma
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| 2008
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发表期刊 | Acta Materialia
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ISSN | 1359-6454
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卷号 | 56期号:14页码:3613-3621 |
摘要 | Using an idealized atomic packing model for metallic glasses (MGs), we predict the binary alloy compositions structurally favorable for the stability of MGs. Such compositions are proposed to be the likely candidates to obtain MGs. The predicted compositions coincide very well with the experimental glass-forming range for a large number of systems. The relationship between these compositions and the eutectic compositions in the equilibrium phase diagrams is established. Direct correlations are found for symmetric eutectic systems, especially for deep eutectics, whereas off-eutectic MGs are suggested for asymmetric eutectic systems. Rationales from the structural standpoint are also presented to explain the increased frequency of appearance of eutectics at certain composition ratios (the Stockdale/Hume-Rothery puzzle). (c) 2008 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved. |
部门归属 | [shi, ling-ling; xu, jian] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china. [ma, evan] johns hopkins univ, dept mat sci & engn, baltimore, md 21218 usa.;xu, j (reprint author), chinese acad sci, inst met res, shenyang natl lab mat sci, 72 wenhua rd, shenyang 110016, peoples r china;jianxu@imr.ac.en cma@jhu.edu
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关键词 | Amorphous Materials
Metallic Glasses
Short-range Order
Modelling
Eutectic
Bulk Amorphous-alloys
Mechanical-properties
Thermal-stability
Cu-zr
Metastable Phases
Atomic Packing
Range Order
Systems
Liquid
Ni
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URL | 查看原文
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WOS记录号 | WOS:000259016600031
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引用统计 |
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文献类型 | 期刊论文
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条目标识符 | http://ir.imr.ac.cn/handle/321006/33072
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专题 | 中国科学院金属研究所
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推荐引用方式 GB/T 7714 |
L. L. Shi,J. Xu,E. Ma. Alloy compositions of metallic glasses and eutectics from an idealized structural model[J]. Acta Materialia,2008,56(14):3613-3621.
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APA |
L. L. Shi,J. Xu,&E. Ma.(2008).Alloy compositions of metallic glasses and eutectics from an idealized structural model.Acta Materialia,56(14),3613-3621.
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MLA |
L. L. Shi,et al."Alloy compositions of metallic glasses and eutectics from an idealized structural model".Acta Materialia 56.14(2008):3613-3621.
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