Studies of EPR theory and trigonal distortion of the (NiX(6))(4-) clusters (X = halide ion) in the series of perovskite crystals AMX(3) (A = Rb, Cs; M = Cd, Mg; X = halide ion)

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	Studies of EPR theory and trigonal distortion of the (NiX(6))(4-) clusters (X = halide ion) in the series of perovskite crystals AMX(3) (A = Rb, Cs; M = Cd, Mg; X = halide ion)
	H. Q. Wang; X. Y. Kuang; H. F. Li
	2008
发表期刊	Chemical Physics Letters
ISSN	0009-2614
卷号	460 期号:1-3 页码:365-369
摘要	A theoretical method is shown to yield a detailed explanation of numerous EPR parameters for d(8) configuration ion in trigonal ligand field. On the basis of the complete energy matrix, the local lattice structures of the octahedral (NiX(6))(4-) clusters in the series of perovskite crystals AMX(3) (A = Rb, Cs; M = Cd, Mg; X = Cl, Br, I) with D(3d) site symmetry have been studied by simulating the EPR and optical spectra. Moreover, the in fluences of the local lattice structure parameters R and h as well as the spin-orbit coupling coefficient zeta on the ZFS parameter D from different systems are discussed. (C) 2008 Elsevier B.V. All rights reserved.
部门归属	[wang, huai-qian; kuang, xiao-yu; li, hui-fang] sichuan univ, inst atom & mol phys, chengdu 610065, peoples r china. [kuang, xiao-yu] acad sinica, int ctr mat phys, shenyang 110016, peoples r china.;kuang, xy (reprint author), sichuan univ, inst atom & mol phys, chengdu 610065, peoples r china;scu_whq@163.com scu_kxy@163.com
关键词	Higher-excited-state Luminescence Properties Spectroscopic Properties Chloride Lattices Resonance-spectra Field Ni2++ Cscdbr3 Cscdcl3 Coordination
URL	查看原文
WOS记录号	WOS:000257596300074
引用统计	被引频次：8[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/33129
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	H. Q. Wang,X. Y. Kuang,H. F. Li. Studies of EPR theory and trigonal distortion of the (NiX(6))(4-) clusters (X = halide ion) in the series of perovskite crystals AMX(3) (A = Rb, Cs; M = Cd, Mg; X = halide ion)[J]. Chemical Physics Letters,2008,460(1-3):365-369.
APA	H. Q. Wang,X. Y. Kuang,&H. F. Li.(2008).Studies of EPR theory and trigonal distortion of the (NiX(6))(4-) clusters (X = halide ion) in the series of perovskite crystals AMX(3) (A = Rb, Cs; M = Cd, Mg; X = halide ion).Chemical Physics Letters,460(1-3),365-369.
MLA	H. Q. Wang,et al."Studies of EPR theory and trigonal distortion of the (NiX(6))(4-) clusters (X = halide ion) in the series of perovskite crystals AMX(3) (A = Rb, Cs; M = Cd, Mg; X = halide ion)".Chemical Physics Letters 460.1-3(2008):365-369.