| Studies of the g factors and the local structure for Ni3+in LaAl0.9Ni0.1O3, La0.75Y0.25Al0.99Ni0.01O3 and YAl0.9Ni0.1O3 | |
| H. M. Zhang; S. Y. Wu; G. D. Lu; Z. H. Zhang; L. H. Wei | |
| 2008 | |
| Source Publication | Radiation Effects and Defects in Solids
 |
| ISSN | 1042-0150 |
| Volume | 163Issue:10Pages:789-794 |
| Abstract | The electron paramagnetic resonance g factors and the local structure for Ni3+ in LaAl0.9Ni0.1O3 (LAN), La0.75Y0.25Al0.99Ni0.01O3 (LYAN) and YAl0.9Ni0.1O3 (YAN) are theoretically studied from the perturbation formulas of the g factors for a 3d7 ion of low spin (S = 1/2) in tetragonally elongated octahedra. In these formulas, the contributions to the g factors from the tetragonal distortion, characterized by the tetragonal field parameters Ds and Dt are taken into account. According to the calculations, the ligand octahedra around Ni3+ are suggested to suffer 2% relative elongation along the [001] (or C4) axis due to the Jahn-Teller effect. |
| description.department | [zhang, hua-ming; wu, shao-yi; lu, guang-duo; zhang, zhi-hong; wei, li-hua] univ elect sci & technol china, dept appl phys, chengdu 610054, peoples r china. [wu, shao-yi] chinese acad sci, int ctr mat phys, shenyang, peoples r china.;wu, sy (reprint author), univ elect sci & technol china, dept appl phys, chengdu 610054, peoples r china;shaoyi_wu@163.com |
| Keyword | Defect Structures Electron Paramagnetic Resonance Crystal-fields And Spin Hamiltonians Ni3++ Laalo3 Layalo3 Yalo3 Atomic Screening Constants Optical-spectra Paramagnetic-resonance Superconducting Tapes Lattice-distortions Superposition Model Scf Functions Cr3++ Ions Crystals Epr |
| URL | 查看原文 |
| WOS ID | WOS:000260608100001 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/33319 |
| Collection | 中国科学院金属研究所 |
| Recommended Citation GB/T 7714 | H. M. Zhang,S. Y. Wu,G. D. Lu,et al. Studies of the g factors and the local structure for Ni3+in LaAl0.9Ni0.1O3, La0.75Y0.25Al0.99Ni0.01O3 and YAl0.9Ni0.1O3[J]. Radiation Effects and Defects in Solids,2008,163(10):789-794. |
| APA | H. M. Zhang,S. Y. Wu,G. D. Lu,Z. H. Zhang,&L. H. Wei.(2008).Studies of the g factors and the local structure for Ni3+in LaAl0.9Ni0.1O3, La0.75Y0.25Al0.99Ni0.01O3 and YAl0.9Ni0.1O3.Radiation Effects and Defects in Solids,163(10),789-794. |
| MLA | H. M. Zhang,et al."Studies of the g factors and the local structure for Ni3+in LaAl0.9Ni0.1O3, La0.75Y0.25Al0.99Ni0.01O3 and YAl0.9Ni0.1O3".Radiation Effects and Defects in Solids 163.10(2008):789-794. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 673.pdf（109KB） | 开放获取 | -- | ||||
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment