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Investigations of EPR parameters for the trigonal Ti3+-Ti3+ pair in beryl crystal
W. Fang; W. C. Zheng
2007
发表期刊Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy
ISSN1386-1425
卷号67期号:5页码:1281-1283
摘要By using the complete diagonalization of energy matrix of 3d(1) ions in trigonal symmetry, the EPR parameters (g factors g(parallel to), g(perpendicular to) and zero-field splitting D) of the trigonal Ti3+-Ti3+ pair in beryl crystal are calculated. In the calculations, the exchange interaction in the Ti3+-Ti3+ pair is taken as the perturbation and the local trigonal distortion in the defect center is considered. The results (which are in agreement with the experimental values) are discussed. (C) 2006 Elsevier B.V. All rights reserved.
部门归属sichuan univ, dept mat sci, chengdu 610064, peoples r china. chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china.;zheng, wc (reprint author), sichuan univ, dept mat sci, chengdu 610064, peoples r china;zhengwc1@163.com
关键词Electron Parameters Resonance Crystal-field Theory Exchange Interaction ti3+-ti3+ Pair Beryl Optical Spectroscopy Ions Cr3++ Fields
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WOS记录号WOS:000248625200019
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被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/33525
专题中国科学院金属研究所
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W. Fang,W. C. Zheng. Investigations of EPR parameters for the trigonal Ti3+-Ti3+ pair in beryl crystal[J]. Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy,2007,67(5):1281-1283.
APA W. Fang,&W. C. Zheng.(2007).Investigations of EPR parameters for the trigonal Ti3+-Ti3+ pair in beryl crystal.Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy,67(5),1281-1283.
MLA W. Fang,et al."Investigations of EPR parameters for the trigonal Ti3+-Ti3+ pair in beryl crystal".Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy 67.5(2007):1281-1283.
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