Electrosynthesis and crystal structure of K3Na(FeO4)(2)

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	Electrosynthesis and crystal structure of K3Na(FeO4)(2)
	W. C. He; X. R. Hu; B. C. Shen; Z. Tang; J. M. Wang; J. Q. Zhang
	2007
发表期刊	Chinese Journal of Inorganic Chemistry
ISSN	1001-4861
卷号	23 期号:4 页码:655-658
摘要	It is reported in this paper for the indirect electrosynthesis of a mixed ferrate(V) crystal, K3Na(FeO4)(2), with a comparatively high purity and its crystal structure is investigated in detail by powders XRD structure analysis. Its chemical formula is ascertained by EDX and AAS. The structure analysis showed that the crystal of K3Na(FeO4)(2) is of hexagonal unit cell, space group P3ml (164), Z=1, 6 atoms of O are located at 6 (i) Wyckoff Sites, 2 atoms of O, Fe and K at 2 (d), respectively, 1 atom of K and Na at 1 (b) and 1 (a), respectively. Cell parameters a=0.5 33 3(1) rim, c=0.755 9(1) nm,D=2.824 g center dot cm(-3). And all inter-atomic distances of K3Na(FeO4)(2) are obtained.
部门归属	zhejiang univ, dept chem, hangzhou 310027, peoples r china. henan med univ, coll mat sci & engn, zhengzhou 450007, peoples r china. zhejiang univ, ctr lab, hangzhou 310028, peoples r china. chinese state key lab corros & protect, shenyang 110015, peoples r china.;wang, jm (reprint author), zhejiang univ, dept chem, hangzhou 310027, peoples r china;wjm@cmsce.zju.edu.cn
关键词	K3na(Feo4)(2) Xrd Structure Analysis Electrosynthesis Electrochemical Performance Physical-properties Charge-transfer Ferrate Iron Electrode K2feo4 Cathodes
URL	查看原文
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/33576
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	W. C. He,X. R. Hu,B. C. Shen,et al. Electrosynthesis and crystal structure of K3Na(FeO4)(2)[J]. Chinese Journal of Inorganic Chemistry,2007,23(4):655-658.
APA	W. C. He,X. R. Hu,B. C. Shen,Z. Tang,J. M. Wang,&J. Q. Zhang.(2007).Electrosynthesis and crystal structure of K3Na(FeO4)(2).Chinese Journal of Inorganic Chemistry,23(4),655-658.
MLA	W. C. He,et al."Electrosynthesis and crystal structure of K3Na(FeO4)(2)".Chinese Journal of Inorganic Chemistry 23.4(2007):655-658.