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The use of doped polyaniline as an electrode in the galvanic anodic protection of ferrous metals in industrial acid solutions
J. Hu; S. Xiao; L. Zhong; H. Zhu; F. Gan
2007
发表期刊Materials and Corrosion-Werkstoffe Und Korrosion
ISSN0947-5117
卷号58期号:10页码:774-780
摘要In order to investigate the galvanic anodic protection (GAP) of ferrous metals (such as 410, 304 and 316 stainless steels) in acid solutions by doped polyaniline (PANi), separate doped PANi powder-pressed electrodes with different surface areas (the area ratio of the PANi electrode to stainless steel is between 1:1 and 1:2) have been prepared. These were coupled with ferrous metal in the following solutions: 5 M sulphuric acid, 5 M phosphoric acid and industrial phosphoric acid (containing 5 M phosphoric acid and 0.05% chloride ion) to construct a galvanic cell, in which PANi is cathode while ferrous metal is anode. The results indicate that a PANi electrode with sufficient area can provide corrosion protection to stainless steel in these acidic solutions. A pilot scale coupling experiment was carried out. The results indicate that PANi is a promising material as an electrode for the anodic protection of ferrous metals in acidic solutions in industrial situations.
部门归属wuhan univ, coll resource & environm sci, wuhan 430072, peoples r china. state key lab corros & protect met, shenyang 110015, peoples r china.;zhu, h (reprint author), wuhan univ, coll resource & environm sci, wuhan 430072, peoples r china;zhuhua333@126.com
关键词Conducting Polymer-coatings Corrosion Protection Stainless-steel Spectroscopy Passivation Performance Mechanism Behavior Primers Films
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WOS记录号WOS:000250736300005
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被引频次:6[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/33586
专题中国科学院金属研究所
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GB/T 7714
J. Hu,S. Xiao,L. Zhong,et al. The use of doped polyaniline as an electrode in the galvanic anodic protection of ferrous metals in industrial acid solutions[J]. Materials and Corrosion-Werkstoffe Und Korrosion,2007,58(10):774-780.
APA J. Hu,S. Xiao,L. Zhong,H. Zhu,&F. Gan.(2007).The use of doped polyaniline as an electrode in the galvanic anodic protection of ferrous metals in industrial acid solutions.Materials and Corrosion-Werkstoffe Und Korrosion,58(10),774-780.
MLA J. Hu,et al."The use of doped polyaniline as an electrode in the galvanic anodic protection of ferrous metals in industrial acid solutions".Materials and Corrosion-Werkstoffe Und Korrosion 58.10(2007):774-780.
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