Theoretical study of local lattice structure of Fe3+-V-M system in iron-doped AMF(3) crystals

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	Theoretical study of local lattice structure of Fe3+-V-M system in iron-doped AMF(3) crystals
	J. H. Li; X. Y. Kuang; M. L. Duan; Z. Y. Jiao
	2007
发表期刊	Chemical Physics Letters
ISSN	0009-2614
卷号	436 期号:1-3 页码:133-138
摘要	A theoretical method for investigating the inter-relation between the electronic and the molecular structures of a d(5) ion in a tetragonal ligand-field has been established on the basis of a 252 x 252 complete energy matrix. Using this method, the local structure parameters of the Fe3+-V-M system in AMF(3):Fe3+ crystals are determined by the experimental EPR spectra at T = 300 K. It is shown that, the local lattice structure around an octahedral Fe3+ center has a compression distortion along the crystalline axis in AMF(3):Fe3+ crystal. From our analysis, we also conclude that Delta R vs. 10(4)b(2)(0) is approximately linear for the Fe3+-V-M system in AMF(3):Fe3+ crystals. (c) 2006 Elsevier B.V. All rights reserved.
部门归属	sichuan univ, inst atom & mol phys, chengdu 610065, peoples r china. acad sinica, int ctr mat phys, shenyang 110016, peoples r china.;kuang, xy (reprint author), sichuan univ, inst atom & mol phys, chengdu 610065, peoples r china;scu_kxy@163.com
关键词	Electron-paramagnetic-resonance Spin-hamiltonian Parameters Epr-spectra Ions Kznf3 Phase Exafs Laser Field Site
URL	查看原文
WOS记录号	WOS:000244946400025
引用统计	被引频次：1[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/33638
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	J. H. Li,X. Y. Kuang,M. L. Duan,et al. Theoretical study of local lattice structure of Fe3+-V-M system in iron-doped AMF(3) crystals[J]. Chemical Physics Letters,2007,436(1-3):133-138.
APA	J. H. Li,X. Y. Kuang,M. L. Duan,&Z. Y. Jiao.(2007).Theoretical study of local lattice structure of Fe3+-V-M system in iron-doped AMF(3) crystals.Chemical Physics Letters,436(1-3),133-138.
MLA	J. H. Li,et al."Theoretical study of local lattice structure of Fe3+-V-M system in iron-doped AMF(3) crystals".Chemical Physics Letters 436.1-3(2007):133-138.