Dual-phase polymer electrolytes based on blending poly(MMA-g-NBR) and PMMA

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	Dual-phase polymer electrolytes based on blending poly(MMA-g-NBR) and PMMA
	W. L. Li; M. J. Yang; M. Y. Yuan; Z. Tang; J. Q. Zhang
	2007
发表期刊	Journal of Applied Polymer Science
ISSN	0021-8995
卷号	106 期号:5 页码:3084-3090
摘要	A new type dual-phase polymer electrolyte (DPE) based on poly(MMA-g-NBR) and poly(methyl methacrylate) (PMMA) was prepared by film-casting method. In the DPE, PMM A phase is selectively impregnated with the lithium salt solution, forming an ion-conducting network, while poly(MMA-g-NBR) phase maintains mechanical strength in the system. With grafting effect, the compatibility of two phases (PMMA/poly(MMA-g-NBR)) can be enhanced obviously. The chemical and physical characteristics, morphology and ionic conductivity behavior of DPEs, and their interfacial stability between lithium metal electrode were characterized by using of FTIR, (HMNR)-H-1, DSC, SEM, optical microscopic images, AC impedance, and linear sweep voltammetry. A new type DPE with good mechanics and high electrochemistry properties is obtained at an optimum proportion of two blending polymers. (c) 2007 Wiley Periodicals, Inc.
部门归属	zhejiang univ, dept polymer sci & engn, hangzhou 310027, peoples r china. zhejiang univ, ctr anal & measurement, hangzhou 310027, peoples r china. zhejiang univ, dept chem, hangzhou 310027, peoples r china. china state key lab corros & protect, shenyang 110015, peoples r china.;yang, mj (reprint author), zhejiang univ, dept polymer sci & engn, hangzhou 310027, peoples r china, peoples r china;yangmj@zju.edu.cn
关键词	Thin Films Blends Electrochemistry Compatibility Ionic-conductivity Mixed Latices Polyacrylonitrile Batteries Methacrylate) Mechanism
URL	查看原文
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/33654
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	W. L. Li,M. J. Yang,M. Y. Yuan,et al. Dual-phase polymer electrolytes based on blending poly(MMA-g-NBR) and PMMA[J]. Journal of Applied Polymer Science,2007,106(5):3084-3090.
APA	W. L. Li,M. J. Yang,M. Y. Yuan,Z. Tang,&J. Q. Zhang.(2007).Dual-phase polymer electrolytes based on blending poly(MMA-g-NBR) and PMMA.Journal of Applied Polymer Science,106(5),3084-3090.
MLA	W. L. Li,et al."Dual-phase polymer electrolytes based on blending poly(MMA-g-NBR) and PMMA".Journal of Applied Polymer Science 106.5(2007):3084-3090.