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High temperature interaction of Al/Si-modified Fe-Cr alloys with KCl
Y. S. Li; Y. Niu; M. Spiegel
2007
Source PublicationCorrosion Science
ISSN0010-938X
Volume49Issue:4Pages:1799-1815
AbstractThe corrosion behaviour of pure iron, pure chromium, and aluminium/silicon alloyed Fe-Cr materials was investigated at 650 degrees C in air accompanied by gaseous or solid KCl salt. The corrosion rates of these materials with KCl salt are high and they are strongly affected by the salt amount, the types of the alloying elements and the concentration of chromium. The dominant degradation mechanism for the chromia-forming alloys by KCl attack is the preferential formation of potassium chromate over the conventionally protective chromia, characterized by typical features of bubbles, cracks, volatility and severe spallation for the corrosion products. A detrimental effect of chromium is confirmed. Al-alloying addition to Fe-Cr alloys is beneficial by enhancing the corrosion resistance. Silicon is more effective in promoting the corrosion resistance of Fe-Cr alloys by forming a stable and dense oxide layer in the inner zone which suppresses the rapid growth of iron oxides. (c) 2006 Elsevier Ltd. All rights reserved.
description.departmentuniv saskatchewan, plasma phys lab, saskatoon, sk s7n 5e2, canada. inst met sci & technol, state key lab corros & protect, shenyang, peoples r china. max planck inst eisenforsch gmbh, d-40237 dusseldorf, germany.;li, ys (reprint author), univ saskatchewan, plasma phys lab, 116 sci pl, saskatoon, sk s7n 5e2, canada;yuanshi_li@yahoo.com
KeywordFe-cr Alloys Kcl High Temperature Corrosion Thermodynamic Diagrams Corrosion Behavior Oxidation Chloride Steel Chromium Silicon Films Nacl Environment Additions
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WOS IDWOS:000245527100009
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Cited Times:70[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/33670
Collection中国科学院金属研究所
Recommended Citation
GB/T 7714
Y. S. Li,Y. Niu,M. Spiegel. High temperature interaction of Al/Si-modified Fe-Cr alloys with KCl[J]. Corrosion Science,2007,49(4):1799-1815.
APA Y. S. Li,Y. Niu,&M. Spiegel.(2007).High temperature interaction of Al/Si-modified Fe-Cr alloys with KCl.Corrosion Science,49(4),1799-1815.
MLA Y. S. Li,et al."High temperature interaction of Al/Si-modified Fe-Cr alloys with KCl".Corrosion Science 49.4(2007):1799-1815.
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