Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (III): Equation of state and fluctuations

IMR OpenIR

	Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (III): Equation of state and fluctuations; Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (III): Equation of state and fluctuations
	H. J. Wang; F. Gu; X. Z. Hong; X. W. Ba
	2007 ; 2007
发表期刊	Science in China Series B-Chemistry ; Science in China Series B-Chemistry
ISSN	1006-9291 ; 1006-9291
卷号	50 期号:2 页码:183-189
摘要	The equation of the state of the hydrogen bonding fluid system of A(a)D(d) type is studied by the principle of statistical mechanics. The influences of hydrogen bonds on the equation of state of the system are obtained based on the change in volume due to hydrogen bonds. Moreover, the number density fluctuations of both molecules and hydrogen bonds as well as their spatial correlation property are investigated. Furthermore, an equation describing relation between the number density correlation function of "molecules-hydrogen bonds" and that of molecules and hydrogen bonds is derived. As application, taking the van der Waals hydrogen bonding fluid as an example, we considered the effect of hydrogen bonds on its relevant statistical properties.; The equation of the state of the hydrogen bonding fluid system of A(a)D(d) type is studied by the principle of statistical mechanics. The influences of hydrogen bonds on the equation of state of the system are obtained based on the change in volume due to hydrogen bonds. Moreover, the number density fluctuations of both molecules and hydrogen bonds as well as their spatial correlation property are investigated. Furthermore, an equation describing relation between the number density correlation function of "molecules-hydrogen bonds" and that of molecules and hydrogen bonds is derived. As application, taking the van der Waals hydrogen bonding fluid as an example, we considered the effect of hydrogen bonds on its relevant statistical properties.
部门归属	hebei univ, coll chem & environm sci, baoding 071002, peoples r china. chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china. hebei univ, coll phys sci & technol, baoding 071002, peoples r china.;wang, hj (reprint author), hebei univ, coll chem & environm sci, baoding 071002, peoples r china;whj@mail.hbu.edu.cn ; hebei univ, coll chem & environm sci, baoding 071002, peoples r china. chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china. hebei univ, coll phys sci & technol, baoding 071002, peoples r china.;wang, hj (reprint author), hebei univ, coll chem & environm sci, baoding 071002, peoples r china;whj@mail.hbu.edu.cn
关键词	Hydrogen Bonding Fluid Hydrogen Bonding Fluid Equation Of State Equation Of State Fluctuation Fluctuation Correlation Correlation Effect Effect Liquid Methanol Liquid Methanol Temperature Temperature Water Water Dependence Dependence
URL	查看原文 ; 查看原文
WOS记录号	WOS:000247154900005 ; WOS:000247154900005
引用统计	被引频次：1[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/33858
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	H. J. Wang,F. Gu,X. Z. Hong,et al. Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (III): Equation of state and fluctuations, Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (III): Equation of state and fluctuations[J]. Science in China Series B-Chemistry, Science in China Series B-Chemistry,2007, 2007,50, 50(2):183-189, 183-189.
APA	H. J. Wang,F. Gu,X. Z. Hong,&X. W. Ba.(2007).Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (III): Equation of state and fluctuations.Science in China Series B-Chemistry,50(2),183-189.
MLA	H. J. Wang,et al."Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (III): Equation of state and fluctuations".Science in China Series B-Chemistry 50.2(2007):183-189.