Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (II): Properties of hydrogen bonding networks

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	Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (II): Properties of hydrogen bonding networks
	H. J. Wang; X. Z. Hong; F. Gu; X. W. Ba
	2007
发表期刊	Science in China Series B-Chemistry
ISSN	1006-9291
卷号	50 期号:1 页码:41230
摘要	Making use of the invariant property of the equilibrium size distribution of the hydrogen bonding clusters formed in hydrogen bonding system of A(a)D(d) type, the analytical expressions of the free energy in pregel and postgel regimes are obtained. Then the gel free energy and the scaling behavior of the number of hydrogen bonds in gel phase near the critical point are investigated to give the corresponding scaling exponents and scaling law. Meanwhile, some properties of intermolecular and intramolecular hydrogen bonds in the system, sol and gel phases are discussed. As a result, the explicit relationship between the number of intramolecular hydrogen bonds and hydrogen bonding degree is obtained.
部门归属	hebei univ, coll chem & environm sci, baoding 071002, peoples r china. chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china. hebei univ, coll phys sci & technol, baoding 071002, peoples r china.;wang, hj (reprint author), hebei univ, coll chem & environm sci, baoding 071002, peoples r china,peoples r china;whj@mail.hbu.edu.cn
关键词	Hydrogen Bonding Network Gel Phase Scaling Thermoreversible Gelation Liquid Water Computer-simulations Dynamics Polymerization Polymers
URL	查看原文
WOS记录号	WOS:000245148000003
引用统计	被引频次：3[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/33860
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	H. J. Wang,X. Z. Hong,F. Gu,et al. Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (II): Properties of hydrogen bonding networks[J]. Science in China Series B-Chemistry,2007,50(1):41230.
APA	H. J. Wang,X. Z. Hong,F. Gu,&X. W. Ba.(2007).Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (II): Properties of hydrogen bonding networks.Science in China Series B-Chemistry,50(1),41230.
MLA	H. J. Wang,et al."Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (II): Properties of hydrogen bonding networks".Science in China Series B-Chemistry 50.1(2007):41230.