The corrosion and electrochemical behaviour of pure aluminium in alkaline methanol solutions

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	The corrosion and electrochemical behaviour of pure aluminium in alkaline methanol solutions
	J. B. Wang; J. M. Wang; H. B. Shao; J. Q. Zhang; C. N. Cao
	2007
发表期刊	Journal of Applied Electrochemistry
ISSN	0021-891X
卷号	37 期号:6 页码:753-758
摘要	The corrosion and electrochemical behaviour of pure aluminium in alkaline methanol solutions has been investigated. The results of hydrogen collection experiments showed that aluminium has a lower corrosion rate in alkaline methanol solutions compared to water based solutions and that the corrosion rate increases with increasing water content of the solution. Polarization and galvanostatic discharge experiments showed that there is a wide potential window of electrochemical activity and a better discharge performance in the alkaline methanol solutions with a certain amount of water. Scanning electron microscopy (SEM) and energy dispersive analysis of X-ray (EDAX) showed that the passivation in the later stages of discharge in alkaline methanol solutions at relatively high current densities is due to the formation of a dense Al(OH)(3) layer on the surface of the anode.
部门归属	zhejiang univ, dept chem, hangzhou 310027, peoples r china. chinese state key lab corros & protect, shenyang 110015, peoples r china.;wang, jm (reprint author), zhejiang univ, dept chem, hangzhou 310027, peoples r china;wjm@cmsce.zju.edu.cn
关键词	Pure Aluminium Alkaline Methanol Solution Corrosion Electrochemical Behaviour Air Batteries Anodic-dissolution Alloying Additives Inhibition Oxide Zinc
URL	查看原文
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/33861
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	J. B. Wang,J. M. Wang,H. B. Shao,et al. The corrosion and electrochemical behaviour of pure aluminium in alkaline methanol solutions[J]. Journal of Applied Electrochemistry,2007,37(6):753-758.
APA	J. B. Wang,J. M. Wang,H. B. Shao,J. Q. Zhang,&C. N. Cao.(2007).The corrosion and electrochemical behaviour of pure aluminium in alkaline methanol solutions.Journal of Applied Electrochemistry,37(6),753-758.
MLA	J. B. Wang,et al."The corrosion and electrochemical behaviour of pure aluminium in alkaline methanol solutions".Journal of Applied Electrochemistry 37.6(2007):753-758.