Study of optical absorption and EPR spectra of Mn2+ ion in cadmium maleate dihydrate

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	Study of optical absorption and EPR spectra of Mn2+ ion in cadmium maleate dihydrate
	X. Yang; X. Y. Kuang; C. Lu; H. Wang
	2007
发表期刊	European Physical Journal D
ISSN	1434-6060
卷号	42 期号:1 页码:35-39
摘要	The optical absorption and EPR spectra of Mn2+ ion doped in cadmium maleate dihydrate have been theoretically investigated by diagonalizing the complete energy matrices for a d(5) configuration ion in a triaonal ligand-field. According to the suggestion of the optical absorption studies, we assume that the Mn2+ ion enters the host lattice interstitially and the distorted octahedral symmetry for the impurity ion is trigonal. Moreover, the local lattice structure parameters of the system are determined. The results show that the six oxygen ions around the Mn2+ ion are at the same distance R = 2.115 angstrom, and there are three Mn-O bonds forming an angle theta(1) of 66.26 degrees with the C-3-axis and three others forming an angle theta(2) of 43.40 degrees.
部门归属	sichuan univ, inst atom & mol phys, chengdu 610065, peoples r china. chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china.;yang, x (reprint author), sichuan univ, inst atom & mol phys, chengdu 610065, peoples r china;yxxy1224@163.com
关键词	Electron-paramagnetic-resonance Single-crystal Carboxylic-acid Complexes Field Systems Salts Fe-3++
URL	查看原文
WOS记录号	WOS:000245788200004
引用统计	被引频次：4[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/33975
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	X. Yang,X. Y. Kuang,C. Lu,et al. Study of optical absorption and EPR spectra of Mn2+ ion in cadmium maleate dihydrate[J]. European Physical Journal D,2007,42(1):35-39.
APA	X. Yang,X. Y. Kuang,C. Lu,&H. Wang.(2007).Study of optical absorption and EPR spectra of Mn2+ ion in cadmium maleate dihydrate.European Physical Journal D,42(1),35-39.
MLA	X. Yang,et al."Study of optical absorption and EPR spectra of Mn2+ ion in cadmium maleate dihydrate".European Physical Journal D 42.1(2007):35-39.