Effect of fluorine ion doping on performance and electrocatalytic activity of PbO2 anodes

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	Effect of fluorine ion doping on performance and electrocatalytic activity of PbO2 anodes
	H. Y. Zhao; J. L. Cao; J. Q. Zhang
	2007
发表期刊	Chinese Journal of Inorganic Chemistry
ISSN	1001-4861
卷号	23 期号:12 页码:2079-2084
摘要	Ti-substrate PbO2 and F-doped PbO2 (F-PbO2) anodes were prepared by thermal decomposition eleetrodeposition technique. The anodes were characterized by XRD and SEM. The electrochemical stability was studied by the accelerated life tests in H2SO4 solution. The results show that the service life of the F-PbO2 anodes is much more longer than that of the undoped anodes. Moreover, the F-PbO2 anodes show a higher degradation rate for 4-chlorphenol (4-CP) than that observed for the PbO2 anodes. The influence of F- doping on the performance and electrocatalytic activity of PbO2 anodes has been discussed. In addition, the degradation mechanism of 4-CP is proposed according to the results of high-performance liquid chromatograph (HPLC).
部门归属	[zhao hai-yan] hebei univ sci & technol, coll sci, shijiazhuang 050018, peoples r china. [cao jiang-lin; zhang jian-qing] zhejiang univ, dept chem, hangzhou 310027, peoples r china. [zhang jian-qing] chinese acad sci, inst met res, state key lab corros & protect, shenyang 110016, peoples r china.;zhao, hy (reprint author), hebei univ sci & technol, coll sci, shijiazhuang 050018, peoples r china;hbhaiyanzh@163.com
关键词	Electrocatalysis F-pbo2 Anodes Degradation 4-chlorphenol Doped Lead Dioxide Physicochemical Properties Electrochemical Oxidation Oxygen Evolution Electrodes Behavior Ozone Acid
URL	查看原文
WOS记录号	WOS:000252503100014
引用统计	被引频次：3[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/34066
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	H. Y. Zhao,J. L. Cao,J. Q. Zhang. Effect of fluorine ion doping on performance and electrocatalytic activity of PbO2 anodes[J]. Chinese Journal of Inorganic Chemistry,2007,23(12):2079-2084.
APA	H. Y. Zhao,J. L. Cao,&J. Q. Zhang.(2007).Effect of fluorine ion doping on performance and electrocatalytic activity of PbO2 anodes.Chinese Journal of Inorganic Chemistry,23(12),2079-2084.
MLA	H. Y. Zhao,et al."Effect of fluorine ion doping on performance and electrocatalytic activity of PbO2 anodes".Chinese Journal of Inorganic Chemistry 23.12(2007):2079-2084.