Synthesis of Mg Ti-2 O-4 by spark plasma sintering | |
B. P. Zhu; Z. Tang; L. H. Zhao; L. L. Wang; C. Z. Li; D. Yin; Z. X. Yu; W. F. Tang; R. Xiong; J. Shi; X. F. Ruan | |
2007 | |
发表期刊 | Materials Letters
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ISSN | 0167-577X |
卷号 | 61期号:2页码:578-581 |
摘要 | We have successfully prepared magnetic frustrated compound Mg[Ti-2]O-4 by a novel technique of spark plasma sintering. X-ray diffraction confirms that the sample is single phase and the spinel parameter a = 8.504(7) angstrom at the room temperature. The magnetic susceptibility shows that an abnormal drop is exhibited at about 254 K, indicating a magnetic single formation, and that a paramagnetic susceptibility increase which obeys the Curie Law appears below about 150 K, revealing that the number of Ti3+ ions which don't take part in spin dimer is about 2.6%. The resistivity shows a jump at the temperature of 254 K, in agreement with the transition temperature of measurement of the susceptibility. (c) 2006 Elsevier B.V All rights reserved. |
部门归属 | wuhan univ, dept phys, wuhan 430072, peoples r china. chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china. wuhan univ, ctr nano sci & technol, wuhan 430072, peoples r china.;shi, j (reprint author), wuhan univ, dept phys, wuhan 430072, peoples r china;jshi@whu.edu.cn |
关键词 | Frustration Spinel Magnetic Susceptibility Sps Transition Liv2o4 Spinel Oxide Ice System Metal |
URL | 查看原文 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/34103 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | B. P. Zhu,Z. Tang,L. H. Zhao,et al. Synthesis of Mg Ti-2 O-4 by spark plasma sintering[J]. Materials Letters,2007,61(2):578-581. |
APA | B. P. Zhu.,Z. Tang.,L. H. Zhao.,L. L. Wang.,C. Z. Li.,...&X. F. Ruan.(2007).Synthesis of Mg Ti-2 O-4 by spark plasma sintering.Materials Letters,61(2),578-581. |
MLA | B. P. Zhu,et al."Synthesis of Mg Ti-2 O-4 by spark plasma sintering".Materials Letters 61.2(2007):578-581. |
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