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Pore structures of multi-walled carbon nanotubes activated by air, CO2 and KOH
Y. Chen; C. Liu; F. Li; H. M. Cheng
2006
发表期刊Journal of Porous Materials
ISSN1380-2224
卷号13期号:2页码:141-146
摘要Multi-walled carbon nanotubes (MWNTs) synthesized by the catalytic decomposition of benzene were activated by KOH, CO2 or air. The adsorption isotherms of the activated MWNTs were analyzed and their pore size distributions were obtained. The results showed that the specific surface areas of the MWNTs activated by KOH, CO2 and air were increased to 785 m(2)/g, 429 m(2)/g and 270 m(2)/g, respectively. The MWNTs activated by KOH were rich in micropores and mesopores, especially high mesopores having volumes up to 1.04 cm(3)/g. The CO2-activated MWNTs also had many micropores while the air-activated MWNTs had a much smaller micropore volume. The morphologies of the activated MWNTs were examined by transmission electron microscopy and high resolution transmission electron microscopy, and the activation mechanisms were discussed.
部门归属chinese acad sci, shenyang natl lab mat sci, inst met res, shenyang 110016, peoples r china.;cheng, hm (reprint author), chinese acad sci, shenyang natl lab mat sci, inst met res, 72 wenhua rd, shenyang 110016, peoples r china;cheng@imr.ac.cn
关键词Carbon Nanotubes Adsorption Electron Microscopy Pore Size Distributions Surface-area Adsorption Hydrogen Deposition Morphology Bundles
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WOS记录号WOS:000236842400006
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被引频次:52[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/34156
专题中国科学院金属研究所
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Y. Chen,C. Liu,F. Li,et al. Pore structures of multi-walled carbon nanotubes activated by air, CO2 and KOH[J]. Journal of Porous Materials,2006,13(2):141-146.
APA Y. Chen,C. Liu,F. Li,&H. M. Cheng.(2006).Pore structures of multi-walled carbon nanotubes activated by air, CO2 and KOH.Journal of Porous Materials,13(2),141-146.
MLA Y. Chen,et al."Pore structures of multi-walled carbon nanotubes activated by air, CO2 and KOH".Journal of Porous Materials 13.2(2006):141-146.
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