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Effects of property of primary droplet on micro-droplet formation; Effects of property of primary droplet on micro-droplet formation
L. H. Liang; Y. L. Jiang; J. Wang
2006 ; 2006
发表期刊Chemical Journal of Chinese Universities-Chinese ; Chemical Journal of Chinese Universities-Chinese
ISSN0251-0790 ; 0251-0790
卷号27期号:11页码:2148-2151
摘要Micro-droplet formation was reported recently that a large amount of tiny water droplets formed around a primary droplet on a corrodible mental surface under suitably higher relative humidity, which may have a close relationship to the atmospheric corrosion initiation. The effect of the property of the primary droplet on the micro-droplet formation and the forming approach of the micro-droplets was investigated by using microscope observation and electrochemical techniques. The results show that no micro-droplets could be observed for the acidic primary droplet with pH value lower than I, and the higher the pH value of the main droplet, the faster the micro-droplets formed, confirming the characteristic of the micro-droplets area with a higher pH value, higher potential and intensive oxygen reduction. In addition, phenolphthalein test and surface tension test proved that the micro-droplets could come from the adsorption and condensation of the water vapor around the primary droplet through the gas phase, instead of through surface spread from the primary droplet. It is under work whether the water vapor for the micro-droplets formation comes form the primary droplet or from humid air directly.; Micro-droplet formation was reported recently that a large amount of tiny water droplets formed around a primary droplet on a corrodible mental surface under suitably higher relative humidity, which may have a close relationship to the atmospheric corrosion initiation. The effect of the property of the primary droplet on the micro-droplet formation and the forming approach of the micro-droplets was investigated by using microscope observation and electrochemical techniques. The results show that no micro-droplets could be observed for the acidic primary droplet with pH value lower than I, and the higher the pH value of the main droplet, the faster the micro-droplets formed, confirming the characteristic of the micro-droplets area with a higher pH value, higher potential and intensive oxygen reduction. In addition, phenolphthalein test and surface tension test proved that the micro-droplets could come from the adsorption and condensation of the water vapor around the primary droplet through the gas phase, instead of through surface spread from the primary droplet. It is under work whether the water vapor for the micro-droplets formation comes form the primary droplet or from humid air directly.
部门归属ocean univ china, coll chem & chem engn, qingdao 266003, peoples r china. state key lab corros & protect met, shenyang 110015, peoples r china.;wang, j (reprint author), ocean univ china, coll chem & chem engn, qingdao 266003, peoples r china;jwang@mail.ouc.edu.cn ; ocean univ china, coll chem & chem engn, qingdao 266003, peoples r china. state key lab corros & protect met, shenyang 110015, peoples r china.;wang, j (reprint author), ocean univ china, coll chem & chem engn, qingdao 266003, peoples r china;jwang@mail.ouc.edu.cn
关键词Micro-droplets Micro-droplets Atmospheric Corrosion Atmospheric Corrosion Polarization Polarization Cathodic Oxygen Cathodic Oxygen Reduction Reduction Atmospheric Corrosion Atmospheric Corrosion Salt Particles Salt Particles Metals Metals Deliquescence Deliquescence
URL查看原文 ; 查看原文
WOS记录号WOS:000242182500037 ; WOS:000242182500037
引用统计
被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/34322
专题中国科学院金属研究所
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GB/T 7714
L. H. Liang,Y. L. Jiang,J. Wang. Effects of property of primary droplet on micro-droplet formation, Effects of property of primary droplet on micro-droplet formation[J]. Chemical Journal of Chinese Universities-Chinese, Chemical Journal of Chinese Universities-Chinese,2006, 2006,27, 27(11):2148-2151, 2148-2151.
APA L. H. Liang,Y. L. Jiang,&J. Wang.(2006).Effects of property of primary droplet on micro-droplet formation.Chemical Journal of Chinese Universities-Chinese,27(11),2148-2151.
MLA L. H. Liang,et al."Effects of property of primary droplet on micro-droplet formation".Chemical Journal of Chinese Universities-Chinese 27.11(2006):2148-2151.
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