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Single-walled carbon nanotubes modified by electrochemical treatment for application in electrochemical capacitors
C. G. Liu; H. T. Fang; F. Li; M. Liu; H. M. Cheng
2006
发表期刊Journal of Power Sources
ISSN0378-7753
卷号160期号:1页码:758-761
摘要An electrochemical process for modifying the pore-size distribution (PSD) of single-walled carbon nanotubes (SWNTs) is developed. The effect of electrochemical treatment time on the PSD of SWNTs is investigated, and the results show that such treatment provides an effective and controllable method for changing the PSD of SWNTs. In particular, a remarkable volume of the small mesopores in the 3.0-5.0 nm diameter range is increased. The SWNTs treated for 24 h at 1.5 V have a higher specific surface-area (109.4 m(2) g(-1)) and larger volume of small mesopores (0.048 cm(3) g(-1) in 3.0-5.0 nm diameter range), compared with the as-grown SWNTs (46.8 m(2) g(-1) and 0.026 cm(3) g(-1), respectively). The as-grown SWNTs and the electrochemically-treated SWNTs are investigated as electrochemical capacitor electrodes, and it is found that the specific capacitance is increased three-fold after electrochemical treatment. (c) 2006 Elsevier B. V All rights reserved.
部门归属chinese acad sci, met res inst, shenyang natl lab mat sci, shenyang 110016, peoples r china. harbin inst technol, sch mat sci & engn, harbin 150001, peoples r china.;cheng, hm (reprint author), chinese acad sci, met res inst, shenyang natl lab mat sci, 72 wenhua rd, shenyang 110016, peoples r china;cheng@imr.ac.cn
关键词Single-walled Carbon Nanotubes Electrochemical Treatment Pore-size Distribution Electrochemical Capacitor Specific Capacitance Mesopores Hydrogen Storage Electrodes Supercapacitors Electrolytes
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WOS记录号WOS:000241067200101
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被引频次:66[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/34340
专题中国科学院金属研究所
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C. G. Liu,H. T. Fang,F. Li,et al. Single-walled carbon nanotubes modified by electrochemical treatment for application in electrochemical capacitors[J]. Journal of Power Sources,2006,160(1):758-761.
APA C. G. Liu,H. T. Fang,F. Li,M. Liu,&H. M. Cheng.(2006).Single-walled carbon nanotubes modified by electrochemical treatment for application in electrochemical capacitors.Journal of Power Sources,160(1),758-761.
MLA C. G. Liu,et al."Single-walled carbon nanotubes modified by electrochemical treatment for application in electrochemical capacitors".Journal of Power Sources 160.1(2006):758-761.
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