Single-walled carbon nanotubes modified by electrochemical treatment for application in electrochemical capacitors | |
C. G. Liu; H. T. Fang; F. Li; M. Liu; H. M. Cheng | |
2006 | |
发表期刊 | Journal of Power Sources
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ISSN | 0378-7753 |
卷号 | 160期号:1页码:758-761 |
摘要 | An electrochemical process for modifying the pore-size distribution (PSD) of single-walled carbon nanotubes (SWNTs) is developed. The effect of electrochemical treatment time on the PSD of SWNTs is investigated, and the results show that such treatment provides an effective and controllable method for changing the PSD of SWNTs. In particular, a remarkable volume of the small mesopores in the 3.0-5.0 nm diameter range is increased. The SWNTs treated for 24 h at 1.5 V have a higher specific surface-area (109.4 m(2) g(-1)) and larger volume of small mesopores (0.048 cm(3) g(-1) in 3.0-5.0 nm diameter range), compared with the as-grown SWNTs (46.8 m(2) g(-1) and 0.026 cm(3) g(-1), respectively). The as-grown SWNTs and the electrochemically-treated SWNTs are investigated as electrochemical capacitor electrodes, and it is found that the specific capacitance is increased three-fold after electrochemical treatment. (c) 2006 Elsevier B. V All rights reserved. |
部门归属 | chinese acad sci, met res inst, shenyang natl lab mat sci, shenyang 110016, peoples r china. harbin inst technol, sch mat sci & engn, harbin 150001, peoples r china.;cheng, hm (reprint author), chinese acad sci, met res inst, shenyang natl lab mat sci, 72 wenhua rd, shenyang 110016, peoples r china;cheng@imr.ac.cn |
关键词 | Single-walled Carbon Nanotubes Electrochemical Treatment Pore-size Distribution Electrochemical Capacitor Specific Capacitance Mesopores Hydrogen Storage Electrodes Supercapacitors Electrolytes |
URL | 查看原文 |
WOS记录号 | WOS:000241067200101 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/34340 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | C. G. Liu,H. T. Fang,F. Li,et al. Single-walled carbon nanotubes modified by electrochemical treatment for application in electrochemical capacitors[J]. Journal of Power Sources,2006,160(1):758-761. |
APA | C. G. Liu,H. T. Fang,F. Li,M. Liu,&H. M. Cheng.(2006).Single-walled carbon nanotubes modified by electrochemical treatment for application in electrochemical capacitors.Journal of Power Sources,160(1),758-761. |
MLA | C. G. Liu,et al."Single-walled carbon nanotubes modified by electrochemical treatment for application in electrochemical capacitors".Journal of Power Sources 160.1(2006):758-761. |
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