| Effect of Na2SO4 and water vapor on the corrosion of Ti3SiC2 | |
| G. M. Liu; M. S. Li; Y. C. Zhou | |
| 2006 | |
| 发表期刊 | Oxidation of Metals
 |
| ISSN | 0030-770X |
| 卷号 | 66期号:1-2页码:115-125 |
| 摘要 | The corrosion behavior of polycrystalline Ti3SiC2 was studied in the presence of Na2SO4 deposit and water vapor at 900 degrees C and 1000 degrees C. The mass gain per unit area of the samples superficially coated with Na2SO4 exposed to water vapor was slightly lower than that of the samples corroded without water vapor. The microstructure and composition of the scales were investigated by SEM/EDS and XRD. Pores were observed in the corroded sample surfaces. The main corrosion phases oil the sample surface were identified by XRD as TiO2, Na2Si2O5 and Na2TiO3. After Ti3SiC2 corroded in the presence of the Na2SO4 deposit and water vapor, the scale had a three-layer microstructure, which was different from the duplex corrosion scale formed on Ti3SiC2 beneath the Na2SO4 film without water vapor. Because water vapor penetrated the Corrosion layer and then reacted with SiO2 to form volatile Si(OH)(4), all intermediate porous and TiO2-enriched layer formed in the corrosion layer. |
| 部门归属 | nanjing inst aeronaut technol, dept mat sci & engn, minist educ, key lab nondestruct test, nanchang 330034, peoples r china. chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china.;liu, gm (reprint author), nanjing inst aeronaut technol, dept mat sci & engn, minist educ, key lab nondestruct test, 173 shanghai rd, nanchang 330034, peoples r china;tisic@126.com |
| 关键词 | Titanium-silicon Carbide Corrosion Na2so4 Water Vapor Titanium-silicon Carbide Hot Corrosion Bulk Ceramics Oxidation Mixture 1000-degrees-c Behavior K2co3 Melts |
| URL | 查看原文 |
| WOS记录号 | WOS:000241896400007 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.imr.ac.cn/handle/321006/34354 |
| 专题 | 中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | G. M. Liu,M. S. Li,Y. C. Zhou. Effect of Na2SO4 and water vapor on the corrosion of Ti3SiC2[J]. Oxidation of Metals,2006,66(1-2):115-125. |
| APA | G. M. Liu,M. S. Li,&Y. C. Zhou.(2006).Effect of Na2SO4 and water vapor on the corrosion of Ti3SiC2.Oxidation of Metals,66(1-2),115-125. |
| MLA | G. M. Liu,et al."Effect of Na2SO4 and water vapor on the corrosion of Ti3SiC2".Oxidation of Metals 66.1-2(2006):115-125. |
| 条目包含的文件 | 条目无相关文件。 | |||||
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