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Protection of iron corrosion by stearic acid and stearic imidazoline self-assembled monolayers
X. Y. Liu; S. H. Chen; H. Y. Ma; G. Z. Liu; L. X. Shen
2006
发表期刊Applied Surface Science
ISSN0169-4332
卷号253期号:2页码:814-820
摘要A type of stearic imidazoline (IM) inhibitor was prepared using stearic acid (SA) and diethylenetriamine (DETA) as raw materials. The monolayers of IM and SA were assembled on the iron surface. The electrochemical characterization of stearic acid (SA) and stearic imidazoline (IM) on an oxide free iron surface had been studied. The monolayers of IM inhibitor were characterized by electrochemical impedance spectroscopy (EIS), electrochemical polarization curves, double layer capacitance, X-ray photoelectron spectroscopy (XPS) and molecular simulation. The results of electrochemical studies had illustrated that the inhibition efficiency of IM was higher than SA. XPS showed that the IM molecules adsorbed on the. iron surface. The molecular simulation calculations showed that the IM molecules were tilted at an angle on the iron surface. (c) 2006 Elsevier B.V. All rights reserved.
部门归属shandong univ, dept chem, jinan 250100, peoples r china. state key lab corros & protect, shenyang 110015, peoples r china.;chen, sh (reprint author), shandong univ, dept chem, jinan 250100, peoples r china;shchen@sdu.edu.cn
关键词Electrochemical Impedance Spectroscopy (Eis) Iron Imidazoline Inhibitor Self-assembled Monolayers (Sams) Carbon-dioxide Corrosion Mild-steel Molecular-structure Multiphase Flow Co2 Corrosion C-steel Inhibition Microstructure Derivatives Impedance
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WOS记录号WOS:000242647800067
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被引频次:78[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/34372
专题中国科学院金属研究所
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X. Y. Liu,S. H. Chen,H. Y. Ma,et al. Protection of iron corrosion by stearic acid and stearic imidazoline self-assembled monolayers[J]. Applied Surface Science,2006,253(2):814-820.
APA X. Y. Liu,S. H. Chen,H. Y. Ma,G. Z. Liu,&L. X. Shen.(2006).Protection of iron corrosion by stearic acid and stearic imidazoline self-assembled monolayers.Applied Surface Science,253(2),814-820.
MLA X. Y. Liu,et al."Protection of iron corrosion by stearic acid and stearic imidazoline self-assembled monolayers".Applied Surface Science 253.2(2006):814-820.
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