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Improving glass-forming ability of Mg-Cu-Y via substitutional alloying: Effects of Ag versus Ni
H. Ma; L. L. Shi; J. Xu; Y. Li; E. Ma
2006
发表期刊Journal of Materials Research
ISSN0884-2914
卷号21期号:9页码:2204-2214
摘要Based on the best bulk metallic glass (BMG) forming alloy in the Mg-Cu-Y ternary system, we introduced Ag (or Ni) to partially substitute for Cu to improve the glass-forming ability (GFA). The objective of this paper is twofold. First, we illustrate in detail a recently developed search strategy, which was proposed but only briefly outlined in our previous publication [H. Ma, L.L. Shi, J. Xu, Y. Li, and E. Ma: Discovering inch-diameter metallic glasses in three-dimensional composition space. Appl. Phys. Lett. 87, 181915 (2005)]. The protocol to navigate in three-dimensional composition space to land large BMGs is spelled out step-by-step using the pseudo-ternary Mg-(Cu,Ag)-Y as the model system. Second, our ability to locate the best BMG former in the composition tetrahedron allows us to systematically examine, and conclude on, the effects of a given alloying element. The large improvement in glass-forming ability in the Mg-(Cu,Ag)-Y system relative to the based ternary will be contrasted with the reduced glass-forming ability in the Mg-(Cu,Ni)-Y pseudo ternary system. It is demonstrated that the improvement of glass-forming ability requires judicious choice of substitutional alloying elements and concentrations, rather than simple additions of multiple elements assuming the "confusion principle."
部门归属chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china. natl univ singapore, dept mat sci & engn, singapore 117675, singapore. johns hopkins univ, dept mat sci & engn, baltimore, md 21218 usa.;xu, j (reprint author), chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china;jianxu@imr.ac.cn
关键词Bulk Metallic-glass Shaped Copper Mold Amorphous-alloys Thermal-stability Ternary-system Casting Method p System Diameter Zr Mm
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WOS记录号WOS:000240578900008
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被引频次:28[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/34394
专题中国科学院金属研究所
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H. Ma,L. L. Shi,J. Xu,et al. Improving glass-forming ability of Mg-Cu-Y via substitutional alloying: Effects of Ag versus Ni[J]. Journal of Materials Research,2006,21(9):2204-2214.
APA H. Ma,L. L. Shi,J. Xu,Y. Li,&E. Ma.(2006).Improving glass-forming ability of Mg-Cu-Y via substitutional alloying: Effects of Ag versus Ni.Journal of Materials Research,21(9),2204-2214.
MLA H. Ma,et al."Improving glass-forming ability of Mg-Cu-Y via substitutional alloying: Effects of Ag versus Ni".Journal of Materials Research 21.9(2006):2204-2214.
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