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Initial deposition mechanism of electroless nickel plating on AZ91D magnesium alloys; Initial deposition mechanism of electroless nickel plating on AZ91D magnesium alloys
Y. Song; D. Shan; E. Han
2006 ; 2006
发表期刊Canadian Metallurgical Quarterly ; Canadian Metallurgical Quarterly
ISSN0008-4433 ; 0008-4433
卷号45期号:2页码:215-222
摘要The pretreatment processes and initial deposition mechanism of electroless nickel plating on AZ91D magnesium alloy were investigated by scanning electron microscopy (SEM) and energy dispersive X-ray (EDX). The results showed that alkaline cleaning could remove the greases and oils from the substrate surface. Acid etching could wipe off the metal chippings and oxides. The hydrofluoric acid activating process which could improve the adhesion of coating to substrate played a key role in the subsequent process of electroless nickel plating. The nickel coating was deposited preferentially on the primary alpha phase and then spread to the eutectic alpha phase and beta phase. The nickel initially nucleated on the primary alpha phase by a replacement reaction, then grew depending on the autocatalysis function of nickel. The coating on the beta phase displayed better adhesion than that on the alpha phase due to the nails fixing effect; The pretreatment processes and initial deposition mechanism of electroless nickel plating on AZ91D magnesium alloy were investigated by scanning electron microscopy (SEM) and energy dispersive X-ray (EDX). The results showed that alkaline cleaning could remove the greases and oils from the substrate surface. Acid etching could wipe off the metal chippings and oxides. The hydrofluoric acid activating process which could improve the adhesion of coating to substrate played a key role in the subsequent process of electroless nickel plating. The nickel coating was deposited preferentially on the primary alpha phase and then spread to the eutectic alpha phase and beta phase. The nickel initially nucleated on the primary alpha phase by a replacement reaction, then grew depending on the autocatalysis function of nickel. The coating on the beta phase displayed better adhesion than that on the alpha phase due to the nails fixing effect
部门归属chinese acad sci, inst met res, environm corros ctr, shenyang, peoples r china.;song, y (reprint author), chinese acad sci, inst met res, environm corros ctr, shenyang, peoples r china ; chinese acad sci, inst met res, environm corros ctr, shenyang, peoples r china.;song, y (reprint author), chinese acad sci, inst met res, environm corros ctr, shenyang, peoples r china
关键词Corrosion Corrosion Pretreatment Pretreatment
URL查看原文 ; 查看原文
WOS记录号WOS:000237502800011 ; WOS:000237502800011
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被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/34460
专题中国科学院金属研究所
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GB/T 7714
Y. Song,D. Shan,E. Han. Initial deposition mechanism of electroless nickel plating on AZ91D magnesium alloys, Initial deposition mechanism of electroless nickel plating on AZ91D magnesium alloys[J]. Canadian Metallurgical Quarterly, Canadian Metallurgical Quarterly,2006, 2006,45, 45(2):215-222, 215-222.
APA Y. Song,D. Shan,&E. Han.(2006).Initial deposition mechanism of electroless nickel plating on AZ91D magnesium alloys.Canadian Metallurgical Quarterly,45(2),215-222.
MLA Y. Song,et al."Initial deposition mechanism of electroless nickel plating on AZ91D magnesium alloys".Canadian Metallurgical Quarterly 45.2(2006):215-222.
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