| Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (I): The geometrical phase transition | |
| H. J. Wang; X. Z. Hong; F. Gu; X. W. Ba | |
| 2006 | |
| Source Publication | Science in China Series B-Chemistry
 |
| ISSN | 1006-9291 |
| Volume | 49Issue:6Pages:499-506 |
| Abstract | The influence of hydrogen bonds on the physical and chemical properties of hydrogen bonding fluid system of A(a)D(d) type is investigated from two viewpoints by the principle of statistical mechanics. In detail, we proposed two new ways that can be used to obtain the equilibrium size distribution of the hydrogen bonding clusters, and derived the analytical expression of a relationship between the hydrogen bonding free energy and hydrogen bonding degree. For the nonlinear hydrogen bonding systems, it is shown that the sol-gel phase transition can take place under proper conditions, which is further proven to be a kind of geometrical phase transition rather than a thermodynamic one. Moreover, several problems associated with the geometrical phase transition and liquid-solid phase transition in nonlinear hydrogen bonding systems are discussed. |
| description.department | hebei univ, coll chem & environm sci, baoding 071002, peoples r china. hebei univ, coll phys sci & technol, baoding 071002, peoples r china. chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china.;wang, hj (reprint author), hebei univ, coll chem & environm sci, baoding 071002, peoples r china;whj@mail.hbu.edu.cn |
| Keyword | Hydrogen Bonding Fluid Equilibrium Free Energy Geometrical Phase Transition Equation-of-state Thermoreversible Gelation Liquid Water Computer-simulations Dynamics Networks Polymers Models |
| URL | 查看原文 |
| WOS ID | WOS:000244104200003 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/34503 |
| Collection | 中国科学院金属研究所 |
| Recommended Citation GB/T 7714 | H. J. Wang,X. Z. Hong,F. Gu,et al. Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (I): The geometrical phase transition[J]. Science in China Series B-Chemistry,2006,49(6):499-506. |
| APA | H. J. Wang,X. Z. Hong,F. Gu,&X. W. Ba.(2006).Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (I): The geometrical phase transition.Science in China Series B-Chemistry,49(6),499-506. |
| MLA | H. J. Wang,et al."Statistical theory for hydrogen bonding fluid system of A(a)D(d) type (I): The geometrical phase transition".Science in China Series B-Chemistry 49.6(2006):499-506. |
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