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A non-classical type of third-element effect in the oxidation of Cu-xCr-2Al alloys at 1173 K
S. Y. Wang; F. Gesmundo; W. T. Wu; Y. Nu
2006
发表期刊Scripta Materialia
ISSN1359-6462
卷号54期号:9页码:1563-1568
摘要Oxidation of a Cu-2.2 at.%Al alloy (Cu-2Al) produces external scales containing Cu-oxides plus some alumina with almost no internal oxidation of aluminum. The addition of 3.9 at.%Cr to Cu-2Al has little effect on the oxidation behavior, while addition of 8.1 at.%Cr promotes a fast formation of an alumina layer in contact with the alloy with a simultaneous large reduction in the oxidation rate. This form of third-element effect, not related to the transition from internal to external oxidation of aluminum but to the inhibition of the copper oxidation, is attributed to the complete solubility between alumina and chromia. (c) 2006 Published by Elsevier Ltd. on behalf of Acta Materialia Inc.
部门归属chinese acad sci, met res inst, state key lab corros & protect, shenyang 110016, peoples r china. univ genoa, dichep, i-16129 genoa, italy.;nu, y (reprint author), chinese acad sci, met res inst, state key lab corros & protect, wencui rd 62, shenyang 110016, peoples r china;yniu@imr.ac.cn
关键词Oxidation Copper Alloys Third-element Effect High-temperature Oxidation High Oxidant Pressures Cu-cr Alloys External Oxidation Binary-alloys Atm O-2 Copper 700-900-degrees-c Legierungen Transition
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WOS记录号WOS:000235865100005
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被引频次:19[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/34525
专题中国科学院金属研究所
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S. Y. Wang,F. Gesmundo,W. T. Wu,et al. A non-classical type of third-element effect in the oxidation of Cu-xCr-2Al alloys at 1173 K[J]. Scripta Materialia,2006,54(9):1563-1568.
APA S. Y. Wang,F. Gesmundo,W. T. Wu,&Y. Nu.(2006).A non-classical type of third-element effect in the oxidation of Cu-xCr-2Al alloys at 1173 K.Scripta Materialia,54(9),1563-1568.
MLA S. Y. Wang,et al."A non-classical type of third-element effect in the oxidation of Cu-xCr-2Al alloys at 1173 K".Scripta Materialia 54.9(2006):1563-1568.
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