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Effect of Sn concentration on the corrosion resistance of Pb-Sn alloys in H2SO4 solution
J. Xu; X. B. Liu; X. G. Li; E. Barbero; C. F. Dong
2006
发表期刊Journal of Power Sources
ISSN0378-7753
卷号155期号:2页码:420-427
摘要The effect of Sn concentration on the corrosion resistance of Pb-Sn alloy in H2SO4 electrolyte was investigated by potentiodynamic polarization. A new approach to calculate the exchange current density, i(corr), was proposed and proved to be in accordance with the experimental results. This study shows that with the increase of alloying Sn, the corrosion rate of the alloy increased and then decreased, with its minimum appearing at 2.60 wt.% Sn. It was also found that the cathodic reaction does not have to be a single-step process, i.e., there are multiple sub-steps involved and complex cations, including H-4(3+) and H-2(+), existing in the systems. (c) 2005 Elsevier B.V. All rights reserved.
部门归属w virginia univ, dept mech & aerosp engn, morgantown, wv 26506 usa. univ sci & technol beijing, ctr corros & protect, beijing 100083, peoples r china. state key lab corros & protect, shenyang 110016, peoples r china.;liu, xb (reprint author), w virginia univ, dept mech & aerosp engn, morgantown, wv 26506 usa;xingbo.liu@mail.wvu.edu
关键词Pb-sn Alloy Potentiodynaic Polarization Corrosion Rate Lead-tin Alloys Sulfuric-acid Electrodes Antimony Behavior Calcium Grids Oxide Sb
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WOS记录号WOS:000237003000042
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被引频次:32[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/34624
专题中国科学院金属研究所
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GB/T 7714
J. Xu,X. B. Liu,X. G. Li,et al. Effect of Sn concentration on the corrosion resistance of Pb-Sn alloys in H2SO4 solution[J]. Journal of Power Sources,2006,155(2):420-427.
APA J. Xu,X. B. Liu,X. G. Li,E. Barbero,&C. F. Dong.(2006).Effect of Sn concentration on the corrosion resistance of Pb-Sn alloys in H2SO4 solution.Journal of Power Sources,155(2),420-427.
MLA J. Xu,et al."Effect of Sn concentration on the corrosion resistance of Pb-Sn alloys in H2SO4 solution".Journal of Power Sources 155.2(2006):420-427.
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