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Effect of microenvironment on the potentiostatic-current oscillation of iron electrode in sulfuric acid solution
X. Yang; S. Chen; C. Wang; L. Li
2006
Source PublicationRussian Journal of Electrochemistry
ISSN1023-1935
Volume42Issue:5Pages:491-496
AbstractPotentiostatic current oscillation of iron electrode in 0.5 mol/l sulfuric acid solution in half open microenvironment is studied. Results show that the microenvironment at the vicinity of the electrode has an important effect on current oscillation. The rate of mass transport of the Fe2+ and H+ can influence the oscillation period: the more difficult the migration of the Fe2+ and H+ ions, the longer the oscillation period. Digital holography is used to study the dynamic changes at the electrode/solution interface during current oscillation. This new method offers a new approach to studying the influence of mass transport on current oscillation.
description.departmentstate key lab corros & protect, shenyang 110015, peoples r china. shandong univ, jinan 250100, peoples r china. xuzhou normal univ, xuzhou 221009, peoples r china.;chen, s (reprint author), state key lab corros & protect, shenyang 110015, peoples r china;shchen@sdu.edu.cn
KeywordCurrent Oscillation Iron Electrode Microenvironment Mass Transport Digital Holography Franck-fitzhugh Model Holographic Microphotography Electrochemical Reaction Solution Interfaces Electrodissolution Dissolution Stability Dynamics System
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WOS IDWOS:000237772000006
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/34647
Collection中国科学院金属研究所
Recommended Citation
GB/T 7714
X. Yang,S. Chen,C. Wang,et al. Effect of microenvironment on the potentiostatic-current oscillation of iron electrode in sulfuric acid solution[J]. Russian Journal of Electrochemistry,2006,42(5):491-496.
APA X. Yang,S. Chen,C. Wang,&L. Li.(2006).Effect of microenvironment on the potentiostatic-current oscillation of iron electrode in sulfuric acid solution.Russian Journal of Electrochemistry,42(5),491-496.
MLA X. Yang,et al."Effect of microenvironment on the potentiostatic-current oscillation of iron electrode in sulfuric acid solution".Russian Journal of Electrochemistry 42.5(2006):491-496.
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