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Effect of particle size on the structure and magnetic properties of La0.6Pb0.4MnO3 nanoparticles
T. Zhang; G. Li; T. Qian; J. F. Qu; X. Q. Xiang; X. G. Li
2006
发表期刊Journal of Applied Physics
ISSN0021-8979
卷号100期号:9
摘要We studied the effect of particle size on the structure and magnetic properties of La0.6Pb0.4MnO3 compounds with particle diameters varying from 5 to 100 nm. With decreasing particle size, the increase of the rhombohedral distortion narrows the bandwidth W-O2p and hence results in the decrease of ferromagnetic transition temperature. At the same time, the magnetic domain structure evolves from multidomain to single domain, and finally a superparamagnetic behavior is detected. The critical single domain size determined by experiment is about 25 nm, and the critical superparamagnetic behavior size obtained by calculation is 5.8 nm. It is found that the variation of coercivity is related to the evolution of magnetic domain states with particle size, and the saturation magnetization decreases significantly due to the increasing contribution of the surface effect with decreasing particle size. (c) 2006 American Institute of Physics.
部门归属univ sci & technol china, hefei natl lab phys sci microscale, anhua 230026, peoples r china. acad sinica, int ctr mat phys, shenyang 110015, peoples r china.;li, xg (reprint author), univ sci & technol china, hefei natl lab phys sci microscale, anhua 230026, peoples r china;lixg@ustc.edu.cn
关键词Optical Phonons Glassy Behavior Magnetoresistance Perovskite Coercivity Lamno3 Raman
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WOS记录号WOS:000242041500102
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被引频次:67[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/34707
专题中国科学院金属研究所
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T. Zhang,G. Li,T. Qian,et al. Effect of particle size on the structure and magnetic properties of La0.6Pb0.4MnO3 nanoparticles[J]. Journal of Applied Physics,2006,100(9).
APA T. Zhang,G. Li,T. Qian,J. F. Qu,X. Q. Xiang,&X. G. Li.(2006).Effect of particle size on the structure and magnetic properties of La0.6Pb0.4MnO3 nanoparticles.Journal of Applied Physics,100(9).
MLA T. Zhang,et al."Effect of particle size on the structure and magnetic properties of La0.6Pb0.4MnO3 nanoparticles".Journal of Applied Physics 100.9(2006).
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