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Effects of hydrogen on the corrosion of pure magnesium
T. Zhang; Y. W. Shao; G. Z. Meng; Y. Li; F. H. Wang
2006
发表期刊Electrochimica Acta
ISSN0013-4686
卷号52期号:3页码:1323-1328
摘要Electrochemical measurements and capacitance measurements were performed for better understanding of the effects of hydrogen on the corrosion of pure magnesium. Anodic polarization curves, activation energy (Ea), pitting initiation time and electrochemical noise (EN) were carried out, which showed that hydrogen had a strong influence on the corrosion of magnesium. There existed a highest corrosion resistance of magnesium, when a series of cathodic charging current density were applied to the specimens due to the optimum hydrogen concentration in the hydride coating (MgH2) on the surface. Mott-Schottky results confirmed that there was a hydride coating on the charged magnesium. Hydrogen ionized as H- and depleted donor/electron, which induced the inversion of semi-conductivity from N-type to P-type. (c) 2006 Elsevier Ltd. All rights reserved.
部门归属harbin engn univ, mech & elect engn inst, corros & protect lab, harbin 150001, peoples r china. chinese acad sci, state key lab corros & protect, inst met res, shenyang 110016, peoples r china.;zhang, t (reprint author), harbin engn univ, mech & elect engn inst, corros & protect lab, nantong st 145, harbin 150001, peoples r china;zhangtao@hrbeu.edu.cn
关键词Magnesium Hydrogen Corrosion Electrochemical Noise Mott-schottky Analysis 310 Stainless-steel Passive Films Alloys
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WOS记录号WOS:000242616100072
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被引频次:28[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/34709
专题中国科学院金属研究所
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T. Zhang,Y. W. Shao,G. Z. Meng,et al. Effects of hydrogen on the corrosion of pure magnesium[J]. Electrochimica Acta,2006,52(3):1323-1328.
APA T. Zhang,Y. W. Shao,G. Z. Meng,Y. Li,&F. H. Wang.(2006).Effects of hydrogen on the corrosion of pure magnesium.Electrochimica Acta,52(3),1323-1328.
MLA T. Zhang,et al."Effects of hydrogen on the corrosion of pure magnesium".Electrochimica Acta 52.3(2006):1323-1328.
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