Zero-field splitting and g-factor studies for 3d(5) ions in tetragonal and trigonal symmetry

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	Zero-field splitting and g-factor studies for 3d(5) ions in tetragonal and trigonal symmetry
	Y. Lei; X. T. Zu; M. G. Zhao
	2005
发表期刊	Physica B-Condensed Matter
ISSN	0921-4526
卷号	364 期号:1-4 页码:122-129
摘要	In this paper, the rigorous analytical expressions for the zero field splittings D, a, F and g-factors of a 3d(5) ion in tetragonal and trigonal crystal fields are derived. In the derivations, the energy levels equivalence between microscopic Zeeman interaction and phenomenological spin-Hamiltonian was used. The deduced expressions do not depend on any interaction model and are universal expressions. As some examples. we studied the specific examples of MnCO3, Rb2CdF4: Mn2+ and KZnF3: Mn2+. Good agreement between calculation and experiments shows that the formulas are reasonable. (c) 2005 Elsevier B.V. All rights reserved.
部门归属	univ elect sci & technol china, dept appl phys, chengdu 610054, peoples r china. chinese acad sci, int ctr mat phys, shenyang 110015, peoples r china. sichuan normal univ, inst solid state phys, chengdu 610066, peoples r china.;zu, xt (reprint author), univ elect sci & technol china, dept appl phys, chengdu 610054, peoples r china;xiaotaozu@yahoo.com
关键词	Crystal-field Theory Zeeman Interaction Spin-hamiltonian Zero Field Splitting Spin-hamiltonian Parameters D-orbital Theory Fluorides Crystals Resonance Pressure Spectrum Cluster Model Fe3++
URL	查看原文
WOS记录号	WOS:000230253100015
引用统计	被引频次：4[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/34893
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	Y. Lei,X. T. Zu,M. G. Zhao. Zero-field splitting and g-factor studies for 3d(5) ions in tetragonal and trigonal symmetry[J]. Physica B-Condensed Matter,2005,364(1-4):122-129.
APA	Y. Lei,X. T. Zu,&M. G. Zhao.(2005).Zero-field splitting and g-factor studies for 3d(5) ions in tetragonal and trigonal symmetry.Physica B-Condensed Matter,364(1-4),122-129.
MLA	Y. Lei,et al."Zero-field splitting and g-factor studies for 3d(5) ions in tetragonal and trigonal symmetry".Physica B-Condensed Matter 364.1-4(2005):122-129.