| Optical properties of (Y1-xTmx)(3)GaO6 and subsolidus phase relation of Y2O3-Ga2O3-Tm2O3 | |
| F. S. Liu; B. J. Sun; J. K. Liang; Q. L. Liu; J. Lub; Y. Zhang; L. X. Wang; J. N. Yao; G. H. Rao | |
| 2005 | |
| Source Publication | Journal of Solid State Chemistry
 |
| ISSN | 0022-4596 |
| Volume | 178Issue:4Pages:1064-1070 |
| Abstract | A serial of samples in Y2O3-Ga2O3-Tm2O3 pseudo-ternary system are prepared by solid-state chemical reaction method. The range of solid solution in (Y1-xTmx)(3)GaO6 is 0 < x < 0.384. Powder X-ray diffraction shows that the compounds crystallize in Gd3GaO6 (Cmc2(1))-type structure. The solid solubilities of Y3+xGa5-xO12 (x = 0-0.77) and Tm3+xGa5-xO12 (x = 0-0.62) are 37.5-47.11 at% Y2O3, and 37.5-45.26 at% Tm2O3, respectively. PL spectra of Tm-doped Y3GaO6 show that there is a sharp blue emission at similar to 456 nm from the D-1(2) -> F-3(4) transition at room temperatures with two lifetimes (similar to 5 and similar to 15 mu s) and a narrow saturation range of PL intensity for the Tm3+ content from x = 0.005 to 0.03. The sharp emission and long lifetime of (Y1-xTmx)(3)GaO6 indicate that Y3GaO6 is a potential phosphor and laser crystal host material. (c) 2005 Elsevier Inc. All rights reserved. |
| description.department | chinese acad sci, inst phys, beijing 100080, peoples r china. chinese acad sci, ctr fis mat condensada, beijing 100080, peoples r china. sw univ sci & technol, sch mat sci & engn, mianyang 621002, peoples r china. acad sinica, int ctr mat phys, shenyang 110016, peoples r china. chinese acad sci, inst chem, beijing 100080, peoples r china.;liu, fs (reprint author), chinese acad sci, inst phys, grp a03,pob 603, beijing 100080, peoples r china;fsliu@aphy.iphy.ac.cn qlliu@aphy.iphy.ac.cn |
| Keyword | Tm3++ -doped Y3gao6 Y2o3-ga2o3-tm2o3 System (Y1-xtmx)(3)Ga5o12 Solid Solution Luminescence Crystal-structure Luminescence Phosphor Cations Ions Tb3 |
| URL | 查看原文 |
| WOS ID | WOS:000229567100016 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/34933 |
| Collection | 中国科学院金属研究所 |
| Recommended Citation GB/T 7714 | F. S. Liu,B. J. Sun,J. K. Liang,et al. Optical properties of (Y1-xTmx)(3)GaO6 and subsolidus phase relation of Y2O3-Ga2O3-Tm2O3[J]. Journal of Solid State Chemistry,2005,178(4):1064-1070. |
| APA | F. S. Liu.,B. J. Sun.,J. K. Liang.,Q. L. Liu.,J. Lub.,...&G. H. Rao.(2005).Optical properties of (Y1-xTmx)(3)GaO6 and subsolidus phase relation of Y2O3-Ga2O3-Tm2O3.Journal of Solid State Chemistry,178(4),1064-1070. |
| MLA | F. S. Liu,et al."Optical properties of (Y1-xTmx)(3)GaO6 and subsolidus phase relation of Y2O3-Ga2O3-Tm2O3".Journal of Solid State Chemistry 178.4(2005):1064-1070. |
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