Effects of A-site doping on microstructure and phase separation of La0.5RE0.2Sr0.3MnO3 (RE=Eu, Ho, Yb, Lu) | |
B. Z. Sun; L. L. He; F. Luo; C. H. Yan | |
2005 | |
Source Publication | Materials Letters
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ISSN | 0167-577X |
Volume | 59Issue:12Pages:1507-1510 |
Abstract | Phase separation and microstructure of La0.7Sr0.3MnO3 doped with rare earth elements (Eu, Ho, Yb and Lu) are studied using X-ray diffraction (XRD) and transmission electron microscopy (TEM). Composition and diffraction analyses demonstrate that the ionic radius of doping element plays an important role in the crystalline structure and the lattice constants of the secondary phase. When La 3 is replaced partly by Eu3+ or Ho3+, orthorhombic perovskite structure with space group Pnma is formed due to the distortion Of MnO6 octahedra. Different from the phenomenon observed by Huang et al., however, the hexagonal non-perovskite structure (YbMnO3 and LuMnO3) has appeared when La3+ and Sr2+ are substituted completely by Lu or Yb (c) 2005 Elsevier B.V. All rights reserved. |
description.department | chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china. peking univ, coll chem & mol engn, pku hku joint lab rare earth mat & bioinorgan che, beijing 100871, peoples r china.;he, ll (reprint author), chinese acad sci, inst met res, shenyang natl lab mat sci, 72 wenhua rd, shenyang 110016, peoples r china;llhe@imr.ac.cn |
Keyword | Ionic Radius Crystalline Structure Lattice Constants Orthorhombic Perovskite Hexagonal Non-perovskite Magnetoresistance Perovskites Films |
URL | 查看原文 |
WOS ID | WOS:000228385500009 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/35041 |
Collection | 中国科学院金属研究所 |
Recommended Citation GB/T 7714 | B. Z. Sun,L. L. He,F. Luo,et al. Effects of A-site doping on microstructure and phase separation of La0.5RE0.2Sr0.3MnO3 (RE=Eu, Ho, Yb, Lu)[J]. Materials Letters,2005,59(12):1507-1510. |
APA | B. Z. Sun,L. L. He,F. Luo,&C. H. Yan.(2005).Effects of A-site doping on microstructure and phase separation of La0.5RE0.2Sr0.3MnO3 (RE=Eu, Ho, Yb, Lu).Materials Letters,59(12),1507-1510. |
MLA | B. Z. Sun,et al."Effects of A-site doping on microstructure and phase separation of La0.5RE0.2Sr0.3MnO3 (RE=Eu, Ho, Yb, Lu)".Materials Letters 59.12(2005):1507-1510. |
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