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Growth of high quality and large-sized Rb0.3MoO3 single crystals by molten salt electrolysis method
J. F. Wang; R. Xiong; F. Yi; D. Yin; M. Z. Ke; C. Z. Li; Z. Y. Liu; J. Shi
2005
发表期刊Journal of Solid State Chemistry
ISSN0022-4596
卷号178期号:5页码:1440-1444
摘要High quality and large-sized Rb0.3MoO3 single crystals were synthesized by molten salt electrolysis method. X-ray diffraction (XRD) patterns and rocking curves, as well as the white beam Laue diffraction of X-ray images show the crystals grown by this method have high quality. The lattice constants evaluated from XRD patterns are a(0) = 1.87 nm, b(0) = 0.75 nm, c(0) = 1.00 nm, β = 118.83(°). The in situ selected area electron diffraction (SAED) patterns along the [10(1) over bar], [1 (11) over bar] and [10(3) over bar] zone axes at room temperature indicate that the Rb0.3MoO3 crystal possess perfect C-centered symmetry. Temperature dependence of the resistivity shows this compound undergoes a metal to semiconductor transition at 183 K. © 2005 Elsevier Inc. All rights reserved.
部门归属wuhan univ, dept phys, wuhan 430072, peoples r china. int ctr mat phys, shenyang 110015, peoples r china.;wang, jf (reprint author), wuhan univ, dept phys, wuhan 430072, peoples r china;janson_iris@163.com
关键词Blue Bronze Rb0.3moo3 Single Crystal Growth Electrolytic Reduction Charge Density Wave Low-dimensional Properties Wave Oxide Rb0.30moo3 Nonlinear Transport Film Growth Blue Bronze K0.30moo3 K0.3moo3 Noise
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WOS记录号WOS:000228934800012
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被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/35076
专题中国科学院金属研究所
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J. F. Wang,R. Xiong,F. Yi,et al. Growth of high quality and large-sized Rb0.3MoO3 single crystals by molten salt electrolysis method[J]. Journal of Solid State Chemistry,2005,178(5):1440-1444.
APA J. F. Wang.,R. Xiong.,F. Yi.,D. Yin.,M. Z. Ke.,...&J. Shi.(2005).Growth of high quality and large-sized Rb0.3MoO3 single crystals by molten salt electrolysis method.Journal of Solid State Chemistry,178(5),1440-1444.
MLA J. F. Wang,et al."Growth of high quality and large-sized Rb0.3MoO3 single crystals by molten salt electrolysis method".Journal of Solid State Chemistry 178.5(2005):1440-1444.
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