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Thermal and electrical properties of new cathode material Ba0.5Sr0.5Co0.8Fe0.2O3-delta for solid oxide fuel cells
B. Wei; Z. Lu; S. Y. Li; Y. Q. Liu; K. Y. Liu; W. H. Su
2005
发表期刊Electrochemical and Solid State Letters
ISSN1099-0062
卷号8期号:8页码:A428-A431
摘要A newly developed cathode material, Ba0.5Sr0.5Co0.8Fe0.2O3-delta, was synthesized and characterized. X-ray diffraction results identified it as a cubic perovskite structure. Thermogravimetric results showed that lattice oxygen loss was about 2% in weight between 50 and 1000 degrees C. Thermal expansion coefficient results in air and argon were extraordinarily high, with slope changes occurring at about 382 and 360 degrees C, respectively. Electrical conductivity values were sufficient for cathode application with the maximum of about 28.1 S cm(-1) at 500 degrees C in air and 17.3 S cm(-1) at 900 degrees C in N-2, correspondingly. Both thermal and electrical properties were closely associated with lattice oxygen behaviors and oxygen partial pressure. (c) 2005 The Electrochemical Society.
部门归属hei long jian provincial univ, harbin inst technol, ctr condensed matter sci & technol, harbin 150001, peoples r china. hei long jian provincial univ, harbin inst technol, key lab condensed matter sci & technol, harbin 150001, peoples r china. jilin univ, dept condensed matter phys, changchun 130023, peoples r china. acad sinica, int ctr mat phys, changchun 110015, peoples r china.;wei, b (reprint author), hei long jian provincial univ, harbin inst technol, ctr condensed matter sci & technol, harbin 150001, peoples r china;lvzhe@hit.edu.cn
关键词Mg-doped Lagao3 Oxygen Permeation Ceramic Membranes Conductivity Electrolyte Expansion Stability System Sofcs
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WOS记录号WOS:000230931300014
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被引频次:146[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/35104
专题中国科学院金属研究所
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B. Wei,Z. Lu,S. Y. Li,et al. Thermal and electrical properties of new cathode material Ba0.5Sr0.5Co0.8Fe0.2O3-delta for solid oxide fuel cells[J]. Electrochemical and Solid State Letters,2005,8(8):A428-A431.
APA B. Wei,Z. Lu,S. Y. Li,Y. Q. Liu,K. Y. Liu,&W. H. Su.(2005).Thermal and electrical properties of new cathode material Ba0.5Sr0.5Co0.8Fe0.2O3-delta for solid oxide fuel cells.Electrochemical and Solid State Letters,8(8),A428-A431.
MLA B. Wei,et al."Thermal and electrical properties of new cathode material Ba0.5Sr0.5Co0.8Fe0.2O3-delta for solid oxide fuel cells".Electrochemical and Solid State Letters 8.8(2005):A428-A431.
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