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Studies of the electric-field-induced zero-field splitting for a substitution Mn2+ ion in SrCl2 crystal
Z. Wen-Chen; T. Sheng; W. Xiao-Xuan
2005
发表期刊Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy
ISSN1386-1425
卷号61期号:5页码:901-904
摘要The zero-field splittings induced by the electric-field have been studied theoretically from the formulas, including three important microscopic mechanisms for a substitutional Mn2+ ion in SrCl2 crystal. From the studies, it is found that the zero-field splitting can be attributed primarily to the electric-field-induced displacement of Mn2+ ion along the electric-field direction and the magnitudes of the displacements at various strengths of electric-field are obtained. The results are comparable with those obtained from the potential-energy curve of Mn2+ center. (C) 2004 Elsevier B.V. All rights reserved.
部门归属sichuan univ, dept mat sci, chengdu 610064, peoples r china. civil aviat flying inst china, dept phys, guanghan 618307, peoples r china. chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china.;wen-chen, z (reprint author), sichuan univ, dept mat sci, chengdu 610064, peoples r china;zhengwc1@163.com
关键词Electron Paramagnetic Resonance (Epr) Electric Field Effect Crystal- And ligAnd-field Theory Mn2++ Srcl2 Theoretical Investigations Covalency Contribution State Parameters Symmetry
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WOS记录号WOS:000227191000016
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/35107
专题中国科学院金属研究所
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Z. Wen-Chen,T. Sheng,W. Xiao-Xuan. Studies of the electric-field-induced zero-field splitting for a substitution Mn2+ ion in SrCl2 crystal[J]. Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy,2005,61(5):901-904.
APA Z. Wen-Chen,T. Sheng,&W. Xiao-Xuan.(2005).Studies of the electric-field-induced zero-field splitting for a substitution Mn2+ ion in SrCl2 crystal.Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy,61(5),901-904.
MLA Z. Wen-Chen,et al."Studies of the electric-field-induced zero-field splitting for a substitution Mn2+ ion in SrCl2 crystal".Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy 61.5(2005):901-904.
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